Silicone-polycarbonate copolymer sealant formulation

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Solution Overview

Problem

Current sealants lack optimal physical and performance properties tailored for specific end-use applications and environments, particularly in terms of curing mechanisms and chemical compositions.

Innovation Solution

A silicone-polycarbonate copolymer with a specific formula Xg[ZjYo]c is developed, comprising silicone and polycarbonate moieties, prepared through methods involving hydrosilylation reactions with polycarbonate compounds and endcapping organosilicon compounds, and used in sealants with a condensation reaction catalyst to form a cured product.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional sealants are used, then basic sealing function is provided, but physical and performance properties are not optimized for specific end-use applications

Engineering Contradiction:
Improveadaptability to specific end-use applicationsVSAvoidperformance properties
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of sealants by incorporating silicone-polycarbonate copolymers with specific formulas (Xg[ZjYo]c) where X represents silicone moieties, Y represents polycarbonate moieties, and Z represents siloxane moieties. By controlling the ratios and types of these moieties, the sealant properties can be tailored to match specific application requirements, resolving the contradiction between adaptability and reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a hybrid sealant material combining silicone-based and polycarbonate components in a copolymer structure. This composite approach allows the sealant to inherit beneficial properties from both parent materials - the flexibility and water resistance of silicone and the mechanical strength and stability of polycarbonate - thereby achieving optimized performance for specific applications.

Inventive Principle:
Principle #40Composite materials

2Reliability

If hybrid materials are utilized, then benefits of silicone-based and organic sealants are combined, but formulation complexity increases

Engineering Contradiction:
Improveperformance propertiesVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the silicone-based and organic sealant benefits into a single integrated copolymer structure rather than combining separate materials. The silicone-polycarbonate copolymer formula Xg[ZjYo]c combines silicone moieties (X), polycarbonate moieties (Y), and siloxane moieties (Z) in one molecular structure, simplifying the formulation process while maintaining the performance benefits of both material systems.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The silicone-polycarbonate copolymer enhances the performance and adaptability of sealants by providing improved mechanical properties and flexibility, allowing for tailored formulations suited to various applications and environments.

Implementation Method 1

reacting a polycarbonate compound having on average more than one unsaturated group and an endcapping organosilicon compound in the presence of a hydrosilylation catalyst to give the silicone-polycarbonate copolymer

Methodology Applied
Scientific EffectHydrosilylation: Chemical Bonding

Implementation Method 2

The sealant comprises a condensation reaction catalyst and further comprises the silicone-polycarbonate copolymer

Methodology Applied
Scientific EffectCondensation reaction: Chemical Bonding

Data Source

PatentUS11760841B2Silicone-polycarbonate copolymer, sealants comprising same, and related methods
Publication Date: 2023.09.19 DOW GLOBAL TECHNOLOGIES LLC
  • US11760841B2 patent drawing
  • US11760841B2 patent drawing
  • US11760841B2 patent drawing

AI summary

A silicone-polycarbonate copolymer has the formula Xg[ZjYo]c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polycarbonate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0≤j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polycarbonate copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polycarbonate copolymer and a condensation-reaction catalyst.