Silicone Polyester Coating for Soft Touch and Anti-Fingerprinting

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Solution Overview

Problem

Coatings for consumer electronic devices often face a trade-off between soft touch properties and anti-fingerprinting performance, with improvements in anti-fingerprinting leading to a deterioration of soft touch properties.

Innovation Solution

A silicone-containing polyester polyol is developed, comprising a reaction product of a diol, a polyol with three or more hydroxyl groups, a dimer of a fatty acid, or its anhydride/ester, and a silicone component with siloxane linkages and reactive functional groups, combined with a crosslinker to form a coating composition that balances soft touch and anti-fingerprinting properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If soft touch coatings are applied to consumer electronic devices, then the soft touch properties are improved, but the anti-fingerprinting properties deteriorate

Engineering Contradiction:
Improvesoft touch propertiesVSAvoidanti-fingerprinting properties
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The invention uses a composite material system combining polyester polyol, silicone component, and crosslinking agent to create a coating that simultaneously achieves soft touch and anti-fingerprinting properties. The polyester polyol provides softness and flexibility, while the silicone component contributes to fingerprint resistance, and the crosslinking agent enhances durability and cleaning performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention optimizes specific parameters including the hydroxyl value of polyester polyol (30-200 mg KOH/g), molecular weight (500-10,000 g/mol), and the ratio of polyester polyol to silicone component (95:5 to 50:50 by weight) to balance soft touch and anti-fingerprinting properties. The crosslinking density and curing conditions are also controlled to achieve the desired performance balance.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If anti-fingerprinting properties are improved in soft touch coatings, then fingerprint resistance is enhanced, but the soft touch properties deteriorate

Engineering Contradiction:
Improveanti-fingerprinting propertiesVSAvoidsoft touch properties
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The invention precisely controls the hydroxyl value of polyester polyol within 30-200 mg KOH/g and molecular weight between 500-10,000 g/mol to maintain softness. The weight ratio of polyester polyol to silicone component is optimized between 95:5 and 50:50, allowing adjustment between soft touch and anti-fingerprinting performance based on application requirements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The coating formulation combines polyester polyol (for softness), silicone component (for fingerprint resistance), and crosslinking agent (for durability) in specific proportions. This composite approach allows the coating to exhibit both soft touch characteristics and enhanced anti-fingerprinting performance without compromising either property.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating composition achieves a balance between soft touch and anti-fingerprinting performance, providing effective anti-fingerprinting while maintaining a soft, smooth feel, as demonstrated by reduced fingerprint visibility and ease of removal, along with improved surface roughness and friction coefficients.

Implementation Method 1

a silicone component comprising siloxane linkages and at least two reactive functional groups selected from hydroxyl groups, phenolic groups, amino groups, thiol groups, carboxylic acid groups, anhydride groups

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

coating composition comprising the silicone-containing polyester polyol and a crosslinker reactive with the silicone-containing polyester polyol

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentEP3548572B1Silicone-containing polyesters, coating compositions containing the same, and coatings formed therefrom
Publication Date: 2021.05.26 PPG INDUSTRIES OHIO INC
  • EP3548572B1 patent drawing
  • EP3548572B1 patent drawing
  • EP3548572B1 patent drawing

AI summary

A silicone-containing polyester polyol can include a reaction product prepared from reactants including: a diol; a polyol having at least three hydroxyl groups; a dimer of a fatty acid having two carboxylic acid groups, or an anhydride or ester thereof; and a silicone component having siloxane linkages and at least two reactive functional groups selected from hydroxyl groups, amino groups, thiol groups, carboxylic acid groups, anhydride groups, or combinations thereof. A coating composition for preparing an anti-fingerprinting, soft touch coating can include the silicone-containing polyester polyol and a crosslinker reactive with the silicone-containing polyester polyol.