Silicone Rubber Composite for Stable Damping Across Temperature

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Solution Overview

Problem

Silicone rubber composite materials face challenges with large temperature dependence of elastic modulus and loss tangent, making it difficult to maintain required characteristics across a wide temperature range, and they often lack durability.

Innovation Solution

A silicone rubber composite material is developed, comprising silicone rubber, first carbon nanotubes with an average diameter of 30 nm or less, and second carbon nanotubes with diameters between 30 nm and 1000 nm, along with graphite pieces, which are kneaded together to achieve reduced temperature dependence and enhanced durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If silicone rubber composite material is used to provide high damping capability (large loss tangent), then damping performance is improved, but temperature dependence of elastic modulus becomes large

Engineering Contradiction:
Improvedamping capabilityVSAvoidtemperature dependence of elastic modulus
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent uses a composite material system consisting of silicone rubber combined with two distinct types of carbon nanotubes (first CNTs with diameter ≤30nm and second CNTs with diameter >30nm and ≤1000nm). This multi-component composite structure allows the material to simultaneously achieve high damping capability through the nanotube-reinforced silicone rubber matrix while maintaining small temperature dependence of elastic modulus through the synergistic interaction between different nanotube sizes and the rubber matrix

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by using carbon nanotubes with different diameter ranges to address different functional requirements. The first carbon nanotubes (≤30nm) primarily contribute to one aspect of performance while the second carbon nanotubes (>30nm and ≤1000nm) contribute to another aspect, allowing each component to optimize its local function within the composite system to collectively resolve the temperature dependence issue

Inventive Principle:
Principle #3Local quality

2Adaptability or versatility

If silicone rubber composite material is designed to maintain performance in wide temperature range, then adaptability is improved, but durability is reduced

Engineering Contradiction:
Improvetemperature range adaptabilityVSAvoiddurability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The composite material system of silicone rubber with dual carbon nanotube types creates a synergistic structure where the nanotubes reinforce the rubber matrix, enabling the material to maintain both wide temperature range adaptability and high durability. The specific diameter ranges of the nanotubes are optimized to provide structural stability across temperatures while preventing degradation

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent specifies precise parameter ranges for the carbon nanotubes (first CNTs: diameter ≤30nm, amount 2.5-10 parts by weight per 100 parts silicone rubber; second CNTs: diameter >30nm and ≤1000nm, amount 5-15 parts by weight per 100 parts silicone rubber). These controlled parameter changes optimize the balance between temperature adaptability and durability by tuning the nanotube size distribution and concentration in the composite

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If carbon nanotubes are added to silicone rubber to reduce temperature dependence, then elastic modulus stability is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveelastic modulus stabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent creates a composite material that achieves elastic modulus stability through the inherent properties of carbon nanotubes embedded in silicone rubber. The two-component nanotube system provides structural reinforcement that stabilizes elastic modulus across temperatures. While the material composition is complex, the manufacturing process leverages standard composite material fabrication techniques, balancing performance gains with practical manufacturability

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material exhibits a small temperature dependence of loss tangent and elastic modulus, maintaining high damping capability and durability over a wide temperature range, effectively addressing the limitations of existing materials.

Implementation Method 1

It is known that these materials exhibit various characteristics by nanonization of substances. Such characteristics are called a nanosize effect as described in Patent Literature 8.

Methodology Applied
Scientific EffectNanosize effect:

Implementation Method 2

a silicone rubber composite material is required to provide high damping capability in some cases. In other words, it is required to provide a large loss tangent in some cases.

Methodology Applied
Scientific EffectDamping: Damping

Data Source

PatentUS11279828B2Silicone rubber composite material and vibration isolating member
Publication Date: 2022.03.22 DENSO CORP
  • US11279828B2 patent drawing
  • US11279828B2 patent drawing
  • US11279828B2 patent drawing

AI summary

A silicone rubber composite material includes silicone rubber, first carbon nanotubes having an average diameter of not more than 30 nm, and second carbon nanotubes having an average diameter of more than 30 nm and not more than 1000 nm. Per 100 parts by weight of the silicone rubber, 2.5 to 10 parts by weight of the first carbon nanotubes and 5 to 15 parts by weight of the second carbon nanotubes are included.