Siloxane Encapsulant Composition for LED Heat Resistance

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Solution Overview

Problem

Conventional encapsulants for light emitting devices, such as LEDs and OLEDs, face challenges in reliability due to limitations in heat resistance and gas permeability, particularly in maintaining transmittance over extended heat treatment periods.

Innovation Solution

A siloxane monomer derived from specific chemical formulas, combined with polysiloxanes, is used to create an encapsulant composition that enhances cross-linking density, thereby improving heat resistance and reducing moisture and oxygen permeability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional encapsulants are used, then the device structure is simple, but heat resistance and gas permeability are insufficient leading to poor reliability

Engineering Contradiction:
ImprovereliabilityVSAvoidcomposition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite materials by combining siloxane monomer, polysiloxane, and crosslinking agent to create an encapsulant composition that achieves superior heat resistance and gas permeability properties while maintaining structural integrity under thermal stress

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes parameter changes through controlling the crosslinking density and molecular structure of the siloxane-based composition, adjusting the ratio of siloxane monomer to polysiloxane and selecting specific crosslinking agents to optimize thermal and barrier properties

Inventive Principle:
Principle #35Parameter changes

2Temperature

If cross-linking density is increased to improve heat resistance, then transmittance degradation is reduced, but gas permeability may be affected

Engineering Contradiction:
Improveheat resistanceVSAvoidgas permeability
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The patent applies local quality by creating a crosslinked network structure that provides different properties in different regions - the crosslinked regions provide heat resistance while the siloxane-based matrix maintains gas permeability control, achieving localized functional optimization

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent controls the degree of crosslinking and molecular parameters to achieve the optimal balance between heat resistance and gas permeability, using specific crosslinking agents and ratios to tune the network density and pore structure

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The encapsulant composition exhibits a transmittance degradation rate of less than or equal to 10% after 1000 hours at 150°C, while simultaneously improving heat resistance and gas permeability, making it suitable for electronic devices.

Implementation Method 1

enhances cross-linking density, improving heat resistance and reducing moisture and oxygen permeability

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Data Source

PatentUS9657174B2Siloxane monomer, encapsulant composition, encapsulant and electronic device
Publication Date: 2017.05.23 CHEIL INDUSTRIES INC
  • US9657174B2 patent drawing
  • US9657174B2 patent drawing
  • US9657174B2 patent drawing

AI summary

A siloxane monomer obtained from a compound represented by Chemical Formula 1 and a compound represented by Chemical Formula 2, an encapsulant composition including the siloxane monomer, an encapsulant obtained by curing the encapsulant composition, and an electronic device including the encapsulant are disclosed.