Siloxane Film Composition for Outdoor Device Adhesion and Transparency

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Solution Overview

Problem

Existing film-forming compositions for outdoor devices and materials, such as monitoring cameras, fail to provide sufficient adhesiveness and transparency, leading to impaired performance due to dirt, dust, and water accumulation.

Innovation Solution

A film-forming composition comprising a hydrolysate of a siloxane compound, silica particles, a ketone-based solvent, and water, along with optional solvents and resins, is applied to form a laminate with enhanced adhesiveness and transparency, inhibiting fogging and facilitating self-cleaning.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If existing film-forming compositions are used, then the coating process is simple, but the adhesiveness and transparency are insufficient

Engineering Contradiction:
Improveadhesiveness and transparencyVSAvoidcomposition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses a composite material system combining siloxane binder, metal oxide particles (TiO2, ZnO, SiO2), and specific solvents to achieve both high adhesiveness and transparency. The metal oxide particles provide antifouling and self-cleaning properties while the siloxane binder ensures strong adhesion, resolving the contradiction between performance and composition complexity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes specific parameters including the content rate of surface-activating components (≥0.5% by mass), metal oxide particle size (0.1-10 μm), and solvent composition (ketone-based + water ± alcohol). These parameter changes enable the composition to achieve excellent adhesiveness and transparency while maintaining antifouling properties.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the film is designed to prevent contamination, then the self-cleaning property is improved, but the light-transmitting properties may deteriorate

Engineering Contradiction:
Improveself-cleaning propertyVSAvoidlight-transmitting properties
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent applies local quality by using metal oxide particles (particularly TiO2 and ZnO) that provide self-cleaning functionality at the surface level while maintaining overall film transparency. The particles are dispersed throughout the coating to create localized photocatalytic activity that breaks down contaminants without significantly affecting light transmission.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent controls the particle size of metal oxides (0.1-10 μm) and their content rate to balance self-cleaning effectiveness with light transmission. By optimizing these parameters, the film achieves both antifouling properties and maintained transparency, resolving the contradiction between self-cleaning and light transmission.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the coating agent forms a hydrophilic film, then the antifouling effect is improved, but the adhesiveness to resin substrate may be reduced

Engineering Contradiction:
Improveantifouling effectVSAvoidadhesiveness
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent uses siloxane binder with specific molecular structure (containing Si-O-Si bonds) that provides both hydrophilicity for antifouling effect and strong adhesion to resin substrates. The content rate of surface-activating components is optimized to ≥0.5% by mass to ensure sufficient hydrophilicity without compromising adhesiveness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite system where siloxane binder provides adhesion and hydrophilicity, while metal oxide particles enhance the antifouling effect through photocatalysis. This composite approach allows the film to achieve both strong adhesiveness and excellent antifouling properties simultaneously.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition forms a film with excellent adhesiveness and transparency, effectively preventing contamination and maintaining performance over time by reducing water contact angles and water absorption, thus ensuring stable operation of outdoor devices and materials.

Implementation Method 1

a film-forming composition comprising a hydrolysate of a siloxane compound

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

forms a film having excellent adhesiveness and transparency... reducing water contact angles and water absorption

Methodology Applied
Scientific EffectHydrophilicity: Hydrophile

Data Source

PatentUS10640670B2Film-forming composition and manufacturing method of laminate
Publication Date: 2020.05.05 FUJIFILM CORP
  • US10640670B2 patent drawing
  • US10640670B2 patent drawing
  • US10640670B2 patent drawing

AI summary

Provided are a film-forming composition containing a hydrolysate of a siloxane compound represented by Formula (1), silica particles, a ketone-based solvent, and water, and a manufacturing method of a laminate. In Formula (1), R1, R2, R3, and R4 each independently represent a monovalent organic group having 1 to 6 carbon atoms. n represents an integer of 2 to 20.