Silver/Silver Chloride Sensor Element with Tailored AgCl Density

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Solution Overview

Problem

Existing medical electrodes suffer from baseline drift due to imbalanced AgCl and Ag levels, leading to electrode failure and waste of valuable silver, especially in long-term use, and there is a need for a design that optimizes AgCl surface density and surface area to extend wear time without excessive silver consumption.

Innovation Solution

A medical electrode with a tailored effective AgCl area density and surface area, determined by the equation ρ A,AgCl = C ⋅ t app ⋅ 1 / A sensor, to ensure stable biopotential signals and minimize silver waste, where ρ A,AgCl is the effective AgCl area density, C is a constant, t app is the wear time, and A sensor is the surface area.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If excessive amounts of silver are used in the sensor element, then reliable biopotential signals can be obtained over long wear times, but valuable silver is wasted and costs increase

Engineering Contradiction:
Improvesignal stabilityVSAvoidsilver waste
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent applies parameter changes by precisely controlling the AgCl area density (ρA,AgCl) and sensor layer surface area (Asensor) to match the specific application time requirements. Instead of using excessive silver universally, the invention tailors these parameters to provide just enough AgCl for the required wear duration, thereby maintaining signal reliability while minimizing silver consumption and waste.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces dynamics by making the sensor design adaptable to different application times. The AgCl area density and surface area are dynamically adjusted based on the specific wear time requirement (tapp), allowing the same electrode design methodology to serve both short-term and long-term applications with optimized silver content for each scenario.

Inventive Principle:
Principle #15Dynamics

2Duration of action of stationary object

If the sensor element is designed for long-term use, then wear time is extended, but baseline drift occurs due to imbalanced AgCl and Ag levels

Engineering Contradiction:
Improvewear timeVSAvoidbaseline stability
Core Design Contradiction:
Duration of action of stationary objectVSStability of the object's composition

Solution Approach 1:

The patent resolves this contradiction by changing the critical parameter of AgCl area density (ρA,AgCl) to ensure sufficient AgCl is available throughout the intended wear time. The equation ρA,AgCl = C · tapp · 1/Asensor directly links the required AgCl density to the application time, preventing baseline drift by maintaining proper AgCl levels even for extended wear periods.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies preliminary action by pre-calculating and incorporating the exact amount of AgCl needed for the desired wear time into the sensor design. This preliminary determination of AgCl requirements ensures that the electrode is properly prepared before use, preventing baseline drift from occurring during the actual wear period.

Inventive Principle:
Principle #10Preliminary action

3Duration of action of stationary object

If the sensor layer surface area is increased, then more AgCl is available to extend wear time, but the amount of silver consumed increases

Engineering Contradiction:
Improvewear timeVSAvoidsilver content
Core Design Contradiction:
Duration of action of stationary objectVSQuantity of substance

Solution Approach 1:

The patent applies parameter changes by optimizing the relationship between AgCl area density (ρA,AgCl) and sensor surface area (Asensor) through the equation ρA,AgCl = C · tapp · 1/Asensor. This allows designers to balance these two parameters according to specific needs - increasing surface area only when necessary for the required wear time, rather than universally increasing silver content.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies local quality by concentrating the AgCl exactly where it is needed - at the sensor surface in contact with the electrolyte gel. By controlling the AgCl area density at the surface rather than uniformly distributing silver throughout the entire sensor structure, the design achieves extended wear time with minimal total silver content.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution allows for high-quality, stable biopotential signals over specified wear times by optimizing AgCl surface density and area, reducing silver waste and preventing baseline drift, applicable to ECG, EMG, and EEG applications.

Implementation Method 1

The electrochemical reaction occurring at the sensor surface may be described as: Ag + Cl- ↔ AgCl + e-

Methodology Applied
Scientific EffectElectrochemical reaction: Redox Reactions

Implementation Method 2

an ion conductive layer, which is in contact with the skin side of a sensor layer in the sensor element

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Data Source

PatentEP4344639B1Silver/silver chloride sensor element
Publication Date: 2025.08.27 AMBU AS
  • EP4344639B1 patent drawingFigure 1
  • EP4344639B1 patent drawingFigure 2a
  • EP4344639B1 patent drawingFigure 2b

AI summary

The present disclosure relates to a medical electrode for biopotential monitoring and/or recording of biopotential signals when attached to the skin of a human or animal. The medical electrode comprises a sensor element and an ion conductive layer, which is in contact with the skin side of a sensor layer in the sensor element. The sensor layer comprises silver (Ag) and silver chloride (AgCI) and has a tailored effective AgCl area density, which depends on the electrode wear time and surface area of the sensor layer.