Sulfonated Polyester Composite Powder with Silver Nanoparticles for SLS

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Solution Overview

Problem

There is a need for antibacterial composite materials suitable for selective laser sintering (SLS) applications, as traditional materials can facilitate bacterial growth due to their layered construction, which is not effectively sterilized by washing alone, especially in healthcare and food industry applications.

Innovation Solution

Development of a composite powder comprising a sulfonated polyester matrix with silver nanoparticles dispersed within, synthesized through a method involving heating the polyester resin in an organic-free solvent, adding silver ions, and using a reducing agent to form silver nanoparticles, which are then aggregated and coalesced to create a composite powder with antibacterial properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional polyamide materials are used for SLS printing, then the material is easy to manufacture and process, but the layered construction facilitates bacterial growth and cannot be effectively sterilized by washing alone

Engineering Contradiction:
Improveease of manufactureVSAvoidbacterial growth
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent uses composite materials by incorporating silver nanoparticles into the polyamide matrix to create a material that maintains the original ease of manufacture while adding antibacterial properties. The silver nanoparticles are dispersed throughout the polymer matrix during the SLS printing process, creating a composite material that is both easy to manufacture and resistant to bacterial growth.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by concentrating silver nanoparticles at the surface and within the layered structure of the printed object. This localized distribution of antibacterial agents directly addresses the bacterial growth problem in crevasses and between layers, while the bulk material retains its original manufacturing characteristics.

Inventive Principle:
Principle #3Local quality

2Object-affected harmful factors

If silver nanoparticles are added to provide antibacterial properties, then bacterial growth is inhibited, but the complexity of the manufacturing process increases

Engineering Contradiction:
Improvebacterial growth inhibitionVSAvoidmanufacturing process complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent merges the antibacterial function with the base polyamide material by incorporating silver nanoparticles into the polymer matrix during the SLS printing process. This combination creates a single integrated material system that provides both structural and antibacterial functions, reducing the need for separate antibacterial coating steps or post-processing treatments.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent employs self-service by using the SLS printing process itself to distribute and embed silver nanoparticles throughout the material. The laser sintering process naturally facilitates the incorporation and uniform distribution of nanoparticles during the layer-by-layer construction, eliminating the need for separate nanoparticle application or distribution steps.

Inventive Principle:
Principle #25Self-service

3Ease of operation

If washing is used to sterilize printed objects, then the process is simple and quick, but it does not completely sterilize surfaces and crevasses of the layered construction

Engineering Contradiction:
Improveease of operationVSAvoidsterilization effectiveness
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies preliminary action by incorporating antibacterial silver nanoparticles into the material during manufacturing, before the object is put into service. This proactive approach ensures that the antibacterial protection is already in place and does not require subsequent sterilization actions, thereby maintaining ease of operation while ensuring reliable sterilization effectiveness.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting composite powder effectively inhibits bacterial growth, providing a stable and efficient antibacterial solution for SLS applications, with silver nanoparticles dispersed throughout the matrix to prevent agglomeration and maintain chemical and mechanical stability, suitable for various applications including medical and food industry uses.

Implementation Method 1

adding a solution of a reducing agent to the mixture, thereby forming an emulsion of particles comprising a sulfonated polyester matrix and a plurality of silver nanoparticles disposed within the sulfonated polyester matrix

Methodology Applied
Scientific EffectReduction: Reduction

Data Source

PatentUS9909013B2Silver nanoparticle-sulfonated polyester composite powders and methods of making the same
Publication Date: 2018.03.06 GENESEE VALLEY INNOVATIONS LLC
  • US9909013B2 patent drawing
  • US9909013B2 patent drawing
  • US9909013B2 patent drawing

AI summary

A composite powder includes a sulfonated polyester matrix and a plurality of silver nanoparticles dispersed within the matrix and methods of making thereof. Various articles can be manufactured from such composite powders.