Silyl Cellulose Thickener for Silane Runoff

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Solution Overview

Problem

Existing hydrophobic silane compositions used for construction materials have low viscosity, making them difficult to apply effectively on vertical surfaces and hazardous to use, with known thickening methods offering limited solutions that can interfere with performance or be incompatible with hydrolyzable silanes.

Innovation Solution

A composition of hydrolyzable organosilanes thickened with alkylsilyl group-containing cellulose, such as trimethylsilyl cellulose, which provides a suitable viscosity for single-pass application on construction materials like concrete, forming a water-resistant film without runoff and being stable in the presence of water.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrolyzable organosilanes are used as hydrophobicizing agents, then water resistance is improved, but viscosity remains low causing runoff and application difficulties

Engineering Contradiction:
Improvewater resistanceVSAvoidapplication ease
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent changes the viscosity parameter of the silane composition by adding a viscosity modifier, transforming it from a low-viscosity liquid that runs off surfaces to a higher-viscosity composition that remains on vertical surfaces for effective penetration and application.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a viscosity modifier as an intermediary substance that mediates between the hydrolyzable organosilane and the application process, enabling proper flow characteristics and surface retention without interfering with the silane's hydrophobicizing function.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If known thickening methods are used, then viscosity is improved, but performance interference or incompatibility with hydrolyzable silanes occurs

Engineering Contradiction:
Improveapplication easeVSAvoidperformance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent carefully selects and adjusts the type and concentration of viscosity modifier to achieve the desired viscosity range while maintaining compatibility with hydrolyzable silanes and avoiding interference with their chemical reactivity and hydrophobicizing performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The viscosity modifier acts as a compatible intermediary that provides thickening functionality without disrupting the chemical properties or reactivity of the hydrolyzable organosilane, unlike previous thickening agents that caused performance issues.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If multiple treatments are applied on sequential days, then water resistance is improved, but time consumption and productivity decrease

Engineering Contradiction:
Improvewater resistanceVSAvoidapplication efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent modifies the viscosity parameter to enable single-pass application with complete surface coverage and penetration, eliminating the need for multiple sequential treatments and thereby significantly improving application efficiency and productivity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The viscosity modifier is pre-added to the silane composition to ensure proper flow and surface retention characteristics before application, allowing complete effective coating in a single pass without requiring follow-up treatments.

Inventive Principle:
Principle #10Preliminary action

4Productivity

If low viscosity silanes are spray applied, then application speed is improved, but safety hazards increase requiring protective equipment

Engineering Contradiction:
Improveapplication speedVSAvoidsafety hazards
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent increases the viscosity parameter of the silane composition to a range that reduces spray drift and airborne mist formation, thereby maintaining application speed while significantly reducing safety hazards and the need for extensive protective equipment.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition allows for efficient, single-pass application of hydrophobic treatments on construction materials, enhancing water resistance and stability, with minimal runoff and interference, while being compatible with existing construction processes.

Implementation Method 1

hydrolyzable organosilane compositions thickened with a cellulosic polymer

Methodology Applied
Scientific EffectThickening:

Implementation Method 2

hydrophobic nature of the silane provides desirable water resistance

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 3

the alkoxy functionality therein to bind to an inorganic material

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 4

their low viscosity makes their application in the field difficult... after runoff an insufficient amount of the material remains on the surface

Methodology Applied
Scientific EffectViscosity stabilization:

Data Source

PatentUS20250011608A1Silyl functional cellulosic rheology modifiers for silanes in construction applications
Publication Date: 2025.01.09 DOW GLOBAL TECHNOLOGIES LLC
  • US20250011608A1 patent drawing

AI summary

The present invention provides thickened hydrolyzable organosilane, such as alkoxyalkyl silane compositions that comprise an alkylsilyl group-containing cellulose thickener having a weight average molecular weight of from 60 to 5000 kDa, such as a trialkylsilyl cellulose. The compositions may comprise neat hydrolyzable organosilanes and from 0.1 to 5 wt. %, based on the total weight of the composition, of the alkylsilyl group-containing cellulose. The compositions having a viscosity resembling paint or coating compositions and are suitable for use as treating or coating compositions that confer water resistance to cementititious substrates.