Single Atom Catalyst Atomic-Level Cocatalyst Control

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Solution Overview

Problem

Heterogeneous photocatalysts face challenges in achieving high efficiency and selectivity due to difficulties in controlling the position and valence of cocatalysts at the atomic level, which is crucial for applications like hydrogen production, CO2 conversion, and water treatment.

Innovation Solution

A single atom catalyst is formed by coating a sacrificial nanoparticle with a first metal oxide, adsorbing a second metal atom, forming a sacrificial layer, and heating, resulting in a catalyst with a second metal atom located in a metal oxide support, allowing for precise atomic composition and improved photocatalytic properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional heterogeneous photocatalysts are used, then catalytic activity can be achieved, but the position and valence of cocatalysts cannot be controlled at the atomic level, resulting in poor selectivity and efficiency

Engineering Contradiction:
Improveposition and valence control of cocatalystsVSAvoidcatalytic efficiency and selectivity
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent applies local quality by creating single atom catalysts where each metal atom is individually positioned and controlled at specific sites on the support surface. This atomic-level precision in local composition allows exact control over the position and valence of cocatalysts, enabling tailored catalytic sites with optimized electronic structures for specific reactions, thereby simultaneously achieving high manufacturing precision and catalytic efficiency

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes parameter changes by varying the oxidation state (valence) of single metal atoms and their local coordination environments on the support. By controlling parameters such as metal atom identity, oxidation state, and neighboring atoms during synthesis, the catalyst's electronic band structure and reactivity can be precisely tuned to optimize both selectivity and catalytic performance for different photocatalytic applications

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the position and valence of cocatalysts are controlled at the atomic level, then catalytic selectivity and efficiency improve, but the complexity of catalyst synthesis and characterization increases

Engineering Contradiction:
Improvecatalytic efficiency and selectivityVSAvoidsynthesis and characterization complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by pre-designing and pre-synthesizing single atom catalysts with controlled metal atom distribution and valence states before catalytic application. The synthesis methods are developed in advance to achieve atomic-level precision, and characterization techniques are established beforehand to verify the atomic structure, thereby simplifying the overall process despite the inherent complexity of atomic-level control

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses intermediary approaches by employing specific support materials and synthesis intermediates that facilitate controlled single atom formation. The support acts as an intermediary that stabilizes single metal atoms at specific sites, while intermediate synthesis steps (such as precursor deposition followed by controlled reduction) serve as mediators to achieve the desired atomic structure without requiring excessively complex direct synthesis methods

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The single atom catalyst achieves enhanced catalytic performance and photocatalytic activity, with the ability to be easily formed and exhibiting unique properties similar to enzyme-like characteristics, significantly improving hydrogen generation and other photocatalytic reactions.

Implementation Method 1

adsorbing a second metal atom to the first metal oxide

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

heating the first metal oxide

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS12251690B2Single atom catalyst and method of forming the same
Publication Date: 2025.03.18 SEOUL NATIONAL UNIVERSITY R&DB FOUNDATION
  • US12251690B2 patent drawing
  • US12251690B2 patent drawing
  • US12251690B2 patent drawing

AI summary

A single atom catalyst and a method of forming the same are provided. The single atom catalyst comprises a support comprising a first metal oxide and a second metal atom located in the first metal oxide. The method of forming the single atom catalyst comprises forming a sacrificial nanoparticle, coating the sacrificial nanoparticle with a first metal oxide, adsorbing a second metal atom to the first metal oxide, forming a sacrificial layer on the support, and heating the first metal oxide.