Single Compressor for CO2 Membrane Separation

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Solution Overview

Problem

Conventional gas separation membrane-based systems for removing CO2 from CO2/hydrocarbon mixtures face economic challenges due to the need for expensive two-stage compression systems when CO2 partial pressures exceed membrane design limits.

Innovation Solution

A three-stage gas separation membrane-based system using a single multi-stage compression unit, where each stage's permeate and residue streams are compressed differently, avoiding membrane plasticization and reducing costs by integrating compression duties within a single compressor system.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single compressor is used to compress both first stage permeate and second stage residue, then device complexity and cost are reduced, but it becomes difficult to independently control the pressure of each stream to meet membrane design limits and product requirements

Engineering Contradiction:
Improvecompression system complexityVSAvoidpressure control flexibility
Core Design Contradiction:
Device complexityVSEase of operation

Solution Approach 1:

The compression system is segmented into multiple independent compression units, each dedicated to compressing specific streams (first stage permeate and second stage residue) to different pressure levels. This segmentation allows independent pressure control for each stream while maintaining overall system simplicity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The compression system is designed with multi-functionality where compression units can serve multiple purposes: compressing permeate streams to feed downstream membranes, compressing residue streams for recycling, and maintaining pressures within membrane design limits. This universal approach reduces overall device complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Ease of operation

If excess pressure is provided in the second residue stream to enable blending with treated natural gas, then ease of operation is improved, but CO2 partial pressure may exceed membrane design limits causing plasticization

Engineering Contradiction:
Improvestream blending capabilityVSAvoidmembrane integrity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The system dynamically adjusts pressure parameters of different streams using independent compression units. The second residue stream pressure is controlled to be sufficient for blending with treated natural gas but not excessive enough to cause CO2 partial pressure to exceed membrane design limits, thus preventing plasticization while maintaining ease of operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The compression system incorporates feedback control mechanisms that monitor CO2 partial pressure and stream composition, adjusting compression ratios to maintain pressure levels that enable easy blending while staying within membrane design limits to prevent plasticization.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively removes CO2 from CO2/hydrocarbon mixtures while maintaining methane enrichment, reducing hydrocarbon losses, and avoiding membrane plasticization, thus being more economical than conventional methods.

Implementation Method 1

Gas separation membranes are used to separate mixtures of carbon dioxide (CO2) and hydrocarbons

Methodology Applied
Scientific EffectSelective permeation: Permeation

Implementation Method 2

membranes arranged in parallel or in series that are selective for CO2 over methane

Methodology Applied
Scientific EffectMembrane selectivity: Semipermeable Membrane

Implementation Method 3

compressing the first permeate in one or more compressors of a multi-stage compression unit

Methodology Applied
Scientific EffectCompression: Compression

Data Source

PatentUS11992804B2Integrated compression and membrane separation process for removal of CO2 from raw natural gas
Publication Date: 2024.05.28 AIR LIQUIDE ADVANCED TECH U S LLC
  • US11992804B2 patent drawing
  • US11992804B2 patent drawing
  • US11992804B2 patent drawing

AI summary

A single compressor is used to separately compress permeate from cascaded first and second gas separation membrane-based separation units and residue from a fourth gas separation membrane-based separation unit in order to avoid too high a CO2 partial pressure in the compressed permeate. After the permeates from the first and second stages are compressed, the compressed stream is fed to a third gas separation membrane-based separation unit.