Single Crystal Alumina Die Attach Paste for LED Thermal Management

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Solution Overview

Problem

Die attach pastes face challenges in achieving high thermal conductivity and anti-yellowing properties while maintaining thin bond line thickness, especially for LED applications, where conventional fillers like small spherical Al2O3 particles fail to meet these requirements.

Innovation Solution

A die attach paste composition comprising an organosilicone resin, single crystal alumina filler with an ellipsoidal shape and high crystallinity, a hardener, and an inhibitor, which enhances thermal conductivity, adhesion strength, and anti-yellowing properties, allowing for thin bond line thickness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of stationary object

If small spherical Al2O3 filler particles are used, then bond line thickness is reduced, but thermal conductivity is insufficient

Engineering Contradiction:
Improvebond line thicknessVSAvoidthermal conductivity
Core Design Contradiction:
Length of stationary objectVSReliability

Solution Approach 1:

The patent changes the particle shape parameter from spherical to ellipsoidal, and the crystallinity parameter from polycrystalline to single crystal. These parameter changes enable the filler to achieve both small size (for thin bond lines) and high thermal conductivity (for effective heat dissipation) simultaneously, resolving the technical contradiction.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses single crystal alumina (Al2O3) as a composite filler material that combines the advantages of high thermal conductivity with appropriate particle morphology. The single crystal structure provides superior thermal transport properties compared to polycrystalline or spherical fillers, while maintaining compatibility with thin bond line requirements.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional fillers are used, then manufacturing cost is reduced, but anti-yellowing properties are insufficient

Engineering Contradiction:
Improvefiller costVSAvoidanti-yellowing properties
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the crystallinity parameter of the alumina filler from conventional polycrystalline to single crystal structure. This parameter change significantly improves the anti-yellowing properties of the die attach paste under LED operating conditions, while the alumina material itself remains cost-effective compared to alternative high-performance fillers like diamond or AlN.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides improved thermal conductivity, excellent anti-yellowing properties, and good adhesion strength, enabling effective heat dissipation and long-term reliability in LED applications with a thin bond line thickness.

Implementation Method 1

Heat dissipation depends on thermal conductivity of die attach paste between the chip and the substrate

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

A die attach paste composition comprising (a) a organosilicone resin

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS9796898B2Single crystal alumina filled die attach paste
Publication Date: 2017.10.24 HENKEL KGAA
  • US9796898B2 patent drawing
  • US9796898B2 patent drawing
  • US9796898B2 patent drawing

AI summary

A die attach paste composition comprising (a) an organosilicone resin; (b) a single crystal alumina filler; (c) a hardener; and (d) an inhibitor. By using single crystal alumina filler in a silicone based die attach paste, thermal conductivity and anti-yellowing properties are improved in comparison with other spherical alumina particles at the same filler loading content.