Single-Crystal Metal AM Using Seeded Epitaxial Solidification

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Solution Overview

Problem

Current additive manufacturing methods cannot produce single-crystal metallic components with arbitrary geometries, as they typically result in polycrystalline structures due to uncontrolled thermal gradients and solidification velocities, limiting the production of high-strength, low-thermal creep materials like nickel-based superalloys used in aerospace and automotive industries.

Innovation Solution

A method involving a metal-containing feedstock and a build plate with a seed single crystal, where the feedstock is melted and solidified under controlled thermal gradients and solidification velocities to produce single-crystal layers, allowing for the creation of additively manufactured single-crystal metallic components with arbitrary composition and orientation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional additive manufacturing is used to build metal components layer by layer, then manufacturing flexibility and design freedom are improved, but the resulting microstructure is polycrystalline with uncontrolled grain structures

Engineering Contradiction:
Improvedesign freedomVSAvoidmicrostructure control
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

A single crystal seed is prepared in advance on the build plate before additive manufacturing begins. This seed crystal establishes the initial crystallographic orientation that will be propagated through subsequent layers, ensuring single-crystal microstructure from the start of the building process

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The thermal gradient and solidification velocity parameters are precisely controlled during additive manufacturing to promote directional solidification. By maintaining specific thermal conditions, the process enables epitaxial growth of single crystal layers from the seed crystal rather than forming random polycrystalline structures

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conventional additive manufacturing processes are used, then production speed and manufacturing time are improved, but single-crystal microstructure cannot be achieved

Engineering Contradiction:
Improvemanufacturing timeVSAvoidsingle-crystal microstructure
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The build plate is pre-prepared with a single crystal seed that establishes the desired crystallographic orientation before manufacturing begins. This preliminary preparation enables single-crystal growth throughout the entire building process without requiring post-processing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The additive manufacturing process continuously deposits material layer by layer while maintaining controlled thermal gradients that promote continuous epitaxial growth. This continuous process allows single-crystal formation throughout the entire component without interruption or re-melting cycles

Inventive Principle:
Principle #20Continuity of useful action

3Device complexity

If polycrystalline structures are produced by additive manufacturing, then manufacturing complexity is reduced, but mechanical strength and thermal creep resistance are limited

Engineering Contradiction:
Improveprocess simplicityVSAvoidmechanical strength
Core Design Contradiction:
Device complexityVSStrength

Solution Approach 1:

By precisely controlling thermal gradient and solidification velocity parameters, the process transforms from producing random polycrystalline structures to achieving directional single-crystal growth. This parameter control enables high-strength single-crystal microstructure without adding complex post-processing steps

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The single crystal seed prepared in advance provides the foundation for high-strength single-crystal growth throughout the component. This preliminary action ensures that the entire component develops a single-crystal microstructure with superior mechanical properties

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the production of single-crystal metallic components with continuous crystallographic textures, overcoming the limitations of traditional additive manufacturing to achieve high-strength and low-thermal creep properties, suitable for applications in aerospace, automotive, and military industries.

Implementation Method 1

exposing a first amount of the metal-containing feedstock to an energy source for melting the first amount of the metal-containing feedstock

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

solidifying the first melt layer, thereby generating a first solid layer

Methodology Applied
Scientific EffectSolidification: Freezing

Implementation Method 3

solidifying the first melt layer, thereby generating a first solid layer... of an additively manufactured single-crystal metallic component

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS12076818B2Additively manufactured single-crystal metallic components, and methods for producing the same
Publication Date: 2024.09.03 HRL LAB
  • US12076818B2 patent drawing
  • US12076818B2 patent drawing
  • US12076818B2 patent drawing

AI summary

Some variations provide a method of making an additively manufactured single-crystal metallic component, comprising: providing a feedstock comprising a first metal or metal alloy; providing a build plate comprising a single crystal of a second metal or metal alloy; exposing the feedstock to an energy source for melting the feedstock, generating a melt layer on the build plate; and solidifying the melt layer, generating a solid layer (on the build plate) of a metal component. The solid layer is also a single crystal of the first metal or metal alloy. The method may be repeated many times to build the part. Some variations provide a single-crystal metallic component comprising a plurality of solid layers in an additive-manufacturing build direction, wherein the plurality of solid layers forms a single crystal of a metal or metal alloy with a continuous crystallographic texture. The crystal orientation may vary along the additive-manufacturing build direction.