Single Gas Phase Reactor Polyolefin Production

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Solution Overview

Problem

Existing polyolefin manufacturing processes using multiple gas phase reactors face challenges in achieving homogeneous polymer production, require frequent inspections due to valve issues, and necessitate additional facilities, leading to inefficiencies and instability.

Innovation Solution

A polyolefin manufacturing apparatus comprising a loop reactor and a single gas phase reactor, where the volume ratio of the gas phase reactor to the loop reactor is 1.2 or more, allowing for continuous polymerization and production of polyolefin with high ethylene-propylene rubber content without the need for multiple gas phase reactors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If multiple gas phase reactors are connected in series to produce high molecular weight polyolefin, then the mechanical properties of the polyolefin are improved, but the homogeneity of the produced polymer is deteriorated due to differences in molecular weight, chemical composition and crystallinity in the respective reactors

Engineering Contradiction:
Improvemechanical propertiesVSAvoidhomogeneity of polymer
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The process is divided into two distinct functional sections: a loop reactor for producing high molecular weight polyolefin and a single gas phase reactor for producing ethylene-propylene rubber. This segmentation allows each reactor to be optimized for its specific function, with the loop reactor maintaining homogeneous conditions for high MW polymer production while the gas phase reactor separately manages rubber production, thereby resolving the homogeneity issue while achieving the desired mechanical properties

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent combines the loop reactor and gas phase reactor into a unified system where the loop reactor produces both polyolefin and ethylene-propylene rubber, which are then fed to the gas phase reactor for final polymerization. This merging approach allows the system to achieve high molecular weight polyolefin with high rubber content (30% or more) while maintaining homogeneity through integrated process control and single gas phase reactor operation

Inventive Principle:
Principle #5Merging (Combining)

2Quantity of substance

If a Double GPR system is used to produce polyolefin with high ethylene-propylene rubber content, then the rubber content is improved, but frequent inspections are required due to valve troubles during particle transfer

Engineering Contradiction:
Improveethylene-propylene rubber contentVSAvoidinspection frequency
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent extracts and eliminates the problematic valve-based particle transfer system by using a single gas phase reactor that receives material directly from the loop reactor without intermediate transfer valves. This removal of the valve component eliminates the source of valve troubles and reduces inspection frequency while maintaining the ability to produce polyolefin with high ethylene-propylene rubber content (30% or more)

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The single gas phase reactor serves multiple functions: it receives polyolefin from the loop reactor, incorporates ethylene-propylene rubber into the polymer matrix, and produces the final high-value polyolefin product. This multi-functionality eliminates the need for separate particle transfer systems and valves, thereby improving reliability and reducing inspection requirements while achieving high rubber content

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Strength

If a Double GPR system is implemented, then high molecular weight polyolefin can be produced, but additional facilities such as recycle compressor, gas separation/recovery facility and particle transfer facility are required

Engineering Contradiction:
Improvemolecular weightVSAvoidadditional facilities
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent merges the functions of multiple facilities into a streamlined system where the loop reactor and single gas phase reactor operate as an integrated unit. The gas phase reactor directly receives material from the loop reactor without requiring separate particle transfer facilities, and the combined system eliminates the need for recycle compressors and gas separation/recovery facilities while still producing high molecular weight polyolefin

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent extracts and removes unnecessary additional facilities (recycle compressor, gas separation/recovery facility, particle transfer facility) by designing a process where the single gas phase reactor directly processes material from the loop reactor. This extraction simplifies the overall system while maintaining the capability to produce high molecular weight polyolefin with high ethylene-propylene rubber content

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enables efficient and stable production of polyolefin with high ethylene-propylene rubber content, improving process efficiency by eliminating the need for additional facilities and reducing the complexity of reactor systems.

Implementation Method 1

an apparatus for producing a prepolymer or a polymer by continuously polymerizing an olefin monomer

Methodology Applied
Scientific EffectPolymerization: Chemical Bonding

Data Source

PatentEP4402183B1Apparatus for manufacturing polyolefin
Publication Date: 2025.06.18 SK INNOVATION CO LTD
  • EP4402183B1 patent drawingFigure 1
  • EP4402183B1 patent drawingFigure 2

AI summary

The present invention provides an apparatus for manufacturing a polyolefin comprising a single gas phase reactor. The apparatus for manufacturing a polyolefin according to exemplary embodiments is an apparatus for producing a prepolymer or a polymer by continuously polymerizing an olefin monomer, and includes: a loop reactor including a first reaction space; and a single gas phase reactor including a second reaction space into which a first product produced in the loop reactor is introduced, wherein the volume ratio of the second reaction space to the first reaction space is adjusted to 1.2 or more. Therefore, it is possible to prepare a polyolefin including high content ethylene-propylene rubber such as impact polypropylene, only by the configuration of a single gas phase reactor without having a plurality of gas phase reactors.