Single-Stage Air Scrubbing for NOx and SOx Conversion

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Solution Overview

Problem

Current methods for removing nitrogen oxides (NOx) and sulfur oxides (SOx) from industrial waste gases are often energy-intensive, bulky, and require multiple stages, making them inefficient and costly for industrial-scale applications.

Innovation Solution

A single-stage air scrubbing apparatus using chlorine dioxide (ClO2) to react with NOx and SOx, introducing turbulence to enhance conversion efficiency, which can operate at various humidity levels and as a cost-effective, easy-to-install solution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional multi-stage methods are used to remove NOx and SOx, then removal effectiveness is improved, but device complexity and operational costs increase

Engineering Contradiction:
Improvepollutant removal effectivenessVSAvoidprocess stage complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple pollutant removal functions into a single reaction chamber where chlorine dioxide simultaneously oxidizes both NOx and SOx. This merging of multiple treatment stages into one integrated system reduces device complexity while maintaining removal effectiveness through the versatile oxidizing capability of chlorine dioxide

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

Chlorine dioxide serves as a universal oxidizing agent that can treat multiple types of pollutants (NOx and SOx) in a single process. This multi-functionality eliminates the need for separate treatment stages for different pollutants, simplifying the overall system while achieving comprehensive pollutant removal

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If conventional methods are used to remove NOx and SOx, then pollutant conversion is achieved, but energy consumption increases

Engineering Contradiction:
Improvepollutant conversion rateVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent changes the chemical parameter by using chlorine dioxide as the oxidizing agent instead of conventional methods. This parameter change enables effective pollutant conversion at lower energy consumption because chlorine dioxide reacts more efficiently with both NOx and SOx, reducing the energy input required for the oxidation process

Inventive Principle:
Principle #35Parameter changes

3Productivity

If turbulence is introduced to enhance conversion, then reaction efficiency is improved, but device complexity increases

Engineering Contradiction:
Improvereaction conversion efficiencyVSAvoidturbulence induction mechanism
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent introduces mechanical turbulence into the reaction chamber to enhance mixing and contact between chlorine dioxide and pollutants. This turbulence, achieved through simple mechanical means such as injection patterns or chamber design, improves reaction efficiency by increasing the interfacial area and mass transfer rate without requiring complex turbulence induction mechanisms

Inventive Principle:
Principle #18Mechanical vibration

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Achieves high conversion rates of NOx and SOx into non-pollutant compounds with a single-stage process, reducing energy consumption and operational costs while being compact and easy to maintain.

Implementation Method 1

A single-stage air scrubbing apparatus using chlorine dioxide (ClO2) to react with NOx and SOx

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

introducing turbulence to enhance conversion efficiency

Methodology Applied
Scientific EffectTurbulence: Turbulence

Data Source

PatentUS20140314648A1Removal of atmospheric pollutants from gas, related apparatus, processes and uses thereof
Publication Date: 2014.10.23 INTELLIGENT ABATEMENT LLC
  • US20140314648A1 patent drawing
  • US20140314648A1 patent drawing
  • US20140314648A1 patent drawing

AI summary

Methods related generally to the removal of atmospheric pollutants from the gas phase, are provided, as well as related apparatus, processes and uses thereof. A single-stage air scrubbing apparatus is provided that includes at least one reaction vessel, at least one introduction duct, and a turbulence component, wherein a residence time is sufficient to allow the conversion of at least one atmospheric pollution compound to at least one other compound, molecule or atom. In some embodiments, the at least one atmospheric pollution compound comprises nitrogen oxide, sulfur oxide or a combination thereof. Additionally, methods of removing atmospheric pollution compounds from a waste gas stream are disclosed that include introducing a waste gas stream and at least one additional gas stream, mist stream, liquid stream or combination thereof into a single-stage air scrubbing apparatus at a flow rate sufficient to allow for conversion of the at least one atmospheric pollution compound.