Single Thread Composite Fiber for Chemical Warfare Agent Degradation

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Solution Overview

Problem

Existing protective garments against chemical warfare agents are either impermeable, causing discomfort and thermal burden, or have low catalyst weight loading, making them inefficient for industrial production and practical use.

Innovation Solution

Development of a single thread composite fiber with a high loading (up to 90%) of catalytic active materials, such as zirconium hydroxide and metal organic frameworks, integrated with a polymeric binder, capable of capturing and degrading toxic agents through absorption, chemisorption, or decomposition, suitable for use in protective garments and filters.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If impermeable membranes are used to prevent molecular diffusion, then protection against chemical warfare agents is improved, but comfort and breathability deteriorate due to thermal burden

Engineering Contradiction:
Improveprotection against chemical warfare agentsVSAvoidcomfort and breathability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent employs porous catalytic materials (such as metal oxides, metal organic frameworks, or activated carbon) integrated into the fabric structure. These porous materials allow gas transport and breathability while providing catalytic sites for chemical degradation, thus maintaining both protection and comfort simultaneously

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent converts the harmful toxic chemicals into beneficial effects by using catalytic materials that promote degradation reactions. The catalytic active materials transform toxic chemical warfare agents into less harmful substances through oxidation, reduction, or hydrolysis reactions, turning the threat into a controlled chemical transformation process

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Reliability

If catalytically active nanocomponents are incorporated into breathable membranes, then protection is maintained, but catalyst weight loading remains low

Engineering Contradiction:
Improveprotection against toxic agentsVSAvoidcatalyst weight loading
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent creates composite materials by combining catalytic active materials (metal oxides, MOFs, or activated carbon) with polymeric binders and matrix materials. This composite approach allows high catalyst loading (up to 90% by weight) while maintaining structural integrity and functional performance, overcoming the limitation of low loading in previous nanocomponent approaches

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physical and chemical parameters of the catalytic materials by using high-surface-area materials and optimizing particle size, morphology, and distribution. These parameter changes enable high catalyst loading while maintaining effectiveness, as the catalytic activity is concentrated in the high-surface-area materials rather than requiring large quantities of bulk catalyst

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The high-loading composite fiber effectively captures and degrades chemical warfare agents and hazardous chemicals, providing enhanced protection while being breathable and suitable for industrial production, improving comfort and efficiency over existing technologies.

Implementation Method 1

reactive with a toxic agent, to absorb, chemisorb, or decompose the toxic agent

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

reactive with a toxic agent, to absorb, chemisorb, or decompose the toxic agent

Methodology Applied
Scientific EffectChemisorption: Chemisorption

Implementation Method 3

catalytic active material reactive with a toxic agent

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

reactive with a toxic agent, to absorb, chemisorb, or decompose the toxic agent

Methodology Applied
Scientific EffectDecomposition: Decomposition (biological)

Data Source

PatentUS11975313B1Single threaded composite fibers and yarns for the degradation of and protection against toxic chemicals and biological agents
Publication Date: 2024.05.07 UNITED STATES OF AMERICA THE AS REPRESENTED BY THE SEC OF THE ARMY
  • US11975313B1 patent drawing
  • US11975313B1 patent drawing
  • US11975313B1 patent drawing

AI summary

The present invention relates to single thread composite fibers comprising at least one binder and at least one active catalyst for the capture and degradation of chemical threats such as chemical warfare agents (CWA), biological warfare agents, and toxic industrial chemicals (TIC) and a method for producing the same. The invention fibers are applicable to the fields of protective garments, filtration materials, and decontamination materials.