Self-Lubricating Sintered Metal Composites via Liquid Phase Agglomeration

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Solution Overview

Problem

Existing self-lubricating composite materials face challenges in achieving high mechanical strength and low friction coefficient due to inadequate dispersion of solid lubricants during the sintering process, leading to structural fragility and reduced lubrication efficiency, especially when using high volumetric percentages of solid lubricants like graphite and hexagonal boron nitride.

Innovation Solution

A metallurgical composition comprising a metallic structural matrix and a non-metallic solid lubricant, where a particulate alloy element forms a liquid phase during sintering, agglomerating the solid lubricant into discrete particles to maintain matrix continuity and prevent solubilization, thereby enhancing mechanical strength and friction reduction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high volumetric percentages of solid lubricants are used, then friction reduction is improved, but mechanical strength deteriorates

Engineering Contradiction:
Improvefriction reductionVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the particle size parameter of solid lubricants to sub-micronic range (0.01-1.0 μm), which allows achieving low friction coefficients while maintaining mechanical strength. The fine particles provide effective lubrication without creating weak zones that would compromise structural integrity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining metallic matrix with sub-micronic solid lubricant particles. This composite structure allows the lubricant particles to be dispersed uniformly throughout the matrix, providing friction reduction while the metallic matrix maintains mechanical strength.

Inventive Principle:
Principle #40Composite materials

2Reliability

If solid lubricant particles are dispersed in the matrix, then lubrication efficiency is improved, but structural continuity deteriorates

Engineering Contradiction:
Improvelubrication efficiencyVSAvoidmatrix continuity
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

By changing the particle size to sub-micronic dimensions and controlling the volumetric percentage (5-30%), the patent achieves uniform dispersion that maintains matrix continuity. The fine particles fit into the matrix structure without creating large discontinuities, preserving both lubrication efficiency and structural integrity.

Inventive Principle:
Principle #35Parameter changes

3Duration of action of moving object

If solid lubricants are incorporated into the material volume, then durability is improved, but manufacturing complexity increases

Engineering Contradiction:
ImprovedurabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
Duration of action of moving objectVSDevice complexity

Solution Approach 1:

The patent merges the solid lubricant incorporation with the sintering process itself. The lubricant particles are mixed with metallic powders before sintering, and the lubrication function is activated automatically during or after sintering through phase transformations or surface reactions, eliminating separate lubrication steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The material structure itself provides the lubrication function through incorporated solid lubricants. The composite material is self-lubricating, eliminating the need for external lubrication systems, separate lubricant application steps, or complex lubrication management.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves sintered products with high mechanical strength, low friction coefficient, and improved durability by ensuring the solid lubricant is dispersed as discrete particles within the matrix, maintaining the structural integrity and lubrication efficiency of the composite material.

Implementation Method 1

at least one particulate material defining a particulate alloy element (chemical element) capable of forming a liquid phase during the sintering

Methodology Applied
Scientific EffectLiquid phase formation: Melting

Implementation Method 2

allowing to reverse, during the sintering, the adverse distribution of the solid lubricant present in the form of a layer... provoking the agglomeration of the solid lubricant in discrete particles

Methodology Applied
Scientific EffectAgglomeration: Coagulation

Implementation Method 3

The liquid phase, which is formed by interdiffusion of the components of the particulate mixture and upon spreading over the particles of the matrix material that are present in the material being formed, penetrates between these particles and the adhered solid lubricant layer, removing said solid lubricant

Methodology Applied
Scientific EffectLiquid phase penetration and removal: Liquid-Liquid Extraction

Implementation Method 4

The invention refers to said metallurgical composition for forming the self-lubricating composite product (pieces), by sintering

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 5

The dry lubrication, that is, the one using solid lubricants, is an alternative to the traditional lubrication, since it acts by the presence of a lubricating layer, which prevents the contact between the component surfaces

Methodology Applied
Scientific EffectDry lubrication: Lubrication

Data Source

PatentUS10166604B2Composition of particulate materials and process for obtaining self-lubricating sintered products
Publication Date: 2019.01.01 EMBRACO IND DE COMPRESSORES E SOLUCOES EM REFRIGERACAO LTDA
  • US10166604B2 patent drawing
  • US10166604B2 patent drawing
  • US10166604B2 patent drawing

AI summary

The metallurgical composition comprises a main particulate metallic material, for example iron or nickel, and at least one alloy element for hardening the main metallic material, which form a structural matrix; a particulate solid lubricant, such as graphite, hexagonal boron nitride or mixture thereof; and a particulate alloy element which is capable of forming, during the sintering of the composition conformed by compaction or by injection molding, a liquid phase, agglomerating the solid lubricant in discrete particles. The composition may comprise an alloy component to stabilize the alpha-iron matrix phase, during the sintering, in order to prevent the graphite solid lubricant from being solubilized in the iron. The invention further refers to the process for obtaining a self-lubricating sintered product.