Sintering Aids for 3D-Printed Metal Part Density

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Solution Overview

Problem

Conventional methods for increasing the density of 3D-printed metal and ceramic parts, such as higher sintering temperatures and hot isostatic pressing, are costly and inefficient, often resulting in parts that are still porous and brittle.

Innovation Solution

Incorporating sintering aids like boron and phosphorus into the metal material, in specific weight fractions, to enhance the density of 3D-printed parts during the sintering process, allowing for reduced sintering temperatures and times while maintaining high density, typically between 90% and 100% of theoretical density.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional sintering methods are used to increase density, then energy consumption increases, but the resulting parts remain porous and brittle

Engineering Contradiction:
Improvepart densityVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent introduces sintering aids (boron, phosphorus, or silicon) as intermediary substances that facilitate the sintering process. These aids lower the sintering temperature required to achieve high density by promoting particle bonding and reducing porosity, thereby resolving the contradiction between achieving high density and minimizing energy consumption.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical composition parameters of the metal material by incorporating sintering aids at specific weight fractions (0.01-1.0 wt%). This compositional modification enables the material to sinter at lower temperatures while achieving higher density, thus reducing energy consumption without compromising part reliability.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If higher sintering temperatures are applied to increase density, then equipment costs and operational complexity increase

Engineering Contradiction:
Improvepart densityVSAvoidequipment requirements
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the material composition by adding sintering aids, which fundamentally changes the sintering temperature parameter required. This allows the use of standard, less complex equipment capable of operating at lower temperatures (below 1200°C) to achieve the same density that would otherwise require complex high-temperature equipment.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If metal powder size is decreased to improve density, then material costs increase and processing difficulty increases

Engineering Contradiction:
Improvepart densityVSAvoidprocessing ease
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The sintering aids act as intermediaries that enhance particle bonding and densification during the sintering process. This allows the use of coarser, easier-to-handle metal powders (90% of particles less than 50 μm, or 18 μm, or 12 μm) to achieve high density parts without requiring ultra-fine powders that are costly and difficult to process.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If hot isostatic pressing is used to increase density, then equipment costs and operational complexity increase

Engineering Contradiction:
Improvepart densityVSAvoidspecialized equipment
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the material composition to include sintering aids that promote densification during conventional sintering. This eliminates the need for hot isostatic pressing equipment by achieving comparable or superior density through modified material behavior at lower pressures and temperatures.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively increases the density of 3D-printed metal parts without the drawbacks of conventional approaches, such as increased energy consumption and equipment costs, while maintaining mechanical and corrosion properties.

Implementation Method 1

Sintering is a process of coalescing a mass of material by application of heat and/or pressure, typically without melting the material to the point of liquefaction. Sintering may be employed for the formation of metal, ceramic, plastic, and other materials.

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS11707781B2Methods of increasing density of 3D-printed and sintered parts
Publication Date: 2023.07.25 MARKFORGED INC
  • US11707781B2 patent drawing
  • US11707781B2 patent drawing
  • US11707781B2 patent drawing

AI summary

A material for producing a three-dimensionally printed part including a metal material and at least one sintering aid in an amount effective to give the three-dimensionally printed part a density of between about 90% and about 100% after sintering is disclosed. A method of printing a three-dimensional part including selecting a metal material, incorporating at least one sintering aid into the metal material to form a print material, and printing the three-dimensional part is also disclosed. A method of producing a sintered metal part including providing a metal material for the sintered metal part incorporating boron as a first sintering aid, incorporating phosphorus as a second sintering aid, forming the metal part in a predetermined form the metal material, and heating the formed metal part to a sintering temperature is also disclosed. Three-dimensionally printed parts are also disclosed.