Six-Membered Ring Compound for Blue OLED Efficiency

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Solution Overview

Problem

Current organic electroluminescent devices, particularly those with organic light emitting layers, face challenges in improving lifetime, efficiency, and operating voltage, with a limited pool of materials suitable for blue light emission.

Innovation Solution

A novel compound with a six-membered ring structure substituted with electron donor, electron acceptor, and sterically demanding groups is developed, which can be used in organic electroluminescent devices to enhance performance and increase the pool of available materials, especially for blue light emission.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic materials are used in OLEDs, then device structure and processing are simple, but lifetime, efficiency and operating voltage need improvement

Engineering Contradiction:
Improvedevice lifetimeVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the chemical structure of organic emitter materials by introducing a six-membered ring core with specific substituent patterns (electron-donating and electron-withdrawing groups at defined positions). This structural parameter change optimizes the material's photophysical properties, leading to improved device lifetime and efficiency while maintaining processability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite molecular structures by combining multiple functional groups (electron donors, electron acceptors, and sterically demanding groups) around a central six-membered ring. This composite approach allows simultaneous optimization of multiple device performance parameters including lifetime, efficiency, and operating voltage

Inventive Principle:
Principle #40Composite materials

2Productivity

If the pool of available materials is limited, then material selection is simple, but efficiency and performance improvement is restricted

Engineering Contradiction:
Improvedevice efficiencyVSAvoidmaterial availability
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The patent segments the emitter material into distinct functional modules: a six-membered ring core (positions 1-6) with specific substituent groups at defined positions. This segmentation allows independent optimization of each module's properties while maintaining overall material performance, thereby expanding the available material pool for achieving high efficiency

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention applies local quality by placing specific electron-donating and electron-withdrawing groups at particular positions around the six-membered ring. This localized functional differentiation enables precise tuning of material properties to achieve desired device efficiency and performance characteristics

Inventive Principle:
Principle #3Local quality

3Illumination intensity

If materials for blue light emission are scarce, then blue emission performance is limited, but expanding material pool requires complex synthesis

Engineering Contradiction:
Improveblue light emissionVSAvoidsynthesis complexity
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The six-membered ring core structure with defined substituent positions serves as a universal platform for generating blue light emission. This multi-functional core can accommodate various electron-donating and electron-withdrawing groups while maintaining blue emission characteristics, simplifying the manufacture of diverse blue-emitting materials from a single core structure

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound improves the performance of organic electroluminescent devices by increasing efficiency and potentially extending their lifetime, while also expanding the range of materials available for these devices, particularly for blue light emission.

Implementation Method 1

The term 'organic electroluminescent device' is generally used for an electronic device which comprises at least one organic material that emits light when an electric current is applied

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP3069392B1Compound with novel six-membered ring structure for use in organic electronic devices
Publication Date: 2019.08.07 MERCK PATENT GMBH
  • EP3069392B1 patent drawing
  • EP3069392B1 patent drawing
  • EP3069392B1 patent drawing

AI summary

The present invention relates to novel compounds according to formula (I) having a six-membered ring structure substituted with electron donor, electron acceptor and sterically demanding groups. Said compound is suited for use in organic electronic devices, particularly in organic electroluminescent devices (OLEDs). Formula (I) wherein Q1 and Q2 are independently of each other selected from the group consisting of N, CRA, CRD, and CRS; Z1 and Z2 are independently of each other selected from the group consisting of N, CRA and CRD; RA is a group with -M-effect; RD is a group with +M-effect; and RS is a sterically demanding group, with the provision that the compound of general formula (I) comprises at least one group CRA and at least one group CRD.