Foaming Slag Former Aggregation and Carbonation Process

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Solution Overview

Problem

The existing methods for preparing foaming slag formers for electric arc furnaces face challenges such as high raw material costs, environmental hazards from solid slag waste, poor flowability, and inefficient recycling of fine metal inclusions, along with safety concerns due to water absorption and explosion risks during introduction into the furnace.

Innovation Solution

The process involves aggregating solid slag particles into coarser grains and carbonating them to produce a foaming slag former with increased flowability and reduced raw material consumption, using industrial flue gases for carbonation, and incorporating additives like sand and carbonaceous materials to enhance gas permeability and safety.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fine solid slag particles are used as foaming agents, then the foaming effect is improved, but the flowability deteriorates and clogging of chutes and trough lances occurs

Engineering Contradiction:
Improvefoaming effectVSAvoidflowability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The invention segments the fine solid slag particles by aggregating them into larger granules or pellets. This segmentation transforms the problematic fine powder into manageable granular material that maintains foaming functionality while improving flowability and preventing clogging of delivery systems.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention introduces an intermediary binding agent that mediates between the fine slag particles and the desired granular structure. This binder facilitates the aggregation of fine particles into larger granules without compromising the chemical composition and foaming properties of the original slag material.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If fine solid slag particles are recycled, then material utilization is improved, but the fine metal inclusions cannot be effectively extracted

Engineering Contradiction:
Improvematerial utilizationVSAvoidmetal inclusion extraction
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

By aggregating fine particles into larger granules, the invention creates a size distribution that facilitates better separation of metal inclusions during subsequent processing. The larger granular structure allows for more effective gravitational separation and magnetic extraction of fine metal inclusions while still utilizing the slag material.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the physical parameter of particle size by aggregating fine particles into larger granules. This parameter change enables improved metal inclusion extraction through enhanced separation efficiency while maintaining high material utilization of the slag component.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If carbonates are used to foam the slag, then the foaming capability is improved, but the raw material cost increases

Engineering Contradiction:
Improvefoaming capabilityVSAvoidraw material cost
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention enables the slag itself to serve as the carbon source for foaming by using the carbonaceous material already present in the solid slag. This self-service approach eliminates the need to import expensive external carbonates, reducing raw material costs while maintaining foaming capability through in-situ carbon monoxide generation.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention converts the previously harmful fine particulate form of recycled slag into a beneficial granular material that simultaneously provides both the structural integrity for handling and the carbon source for foaming. This transformation turns the waste disposal problem into a valuable resource that eliminates the need for expensive carbonate additives.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Ease of manufacture

If solid slag is disposed of as waste, then the production process is simplified, but environmental hazards from heavy metals and halogens increase

Engineering Contradiction:
Improveprocess simplicityVSAvoidenvironmental hazard
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

Instead of simply discarding solid slag as waste, the invention recovers and reuses it as a valuable raw material for producing foaming granules. This recovery process transforms an environmental hazard into a useful resource, eliminating heavy metal and halogen disposal problems while maintaining process efficiency.

Inventive Principle:
Principle #34Discarding and recovering

Solution Approach 2:

The invention converts the harmful waste slag containing heavy metals and halogens into a beneficial foaming agent. By aggregating and carbonating the slag, the process transforms an environmental liability into a functional material that provides both foaming capability and thermal insulation while preventing pollutant leaching into the environment.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a safer, more effective, and environmentally friendly foaming slag former with improved handling and thermal insulation, reduced waste disposal issues, and increased gas volume in the molten slag, while recycling valuable materials and utilizing greenhouse gases.

Implementation Method 1

aggregating solid slag particles to form a granular material formed by coarser grains

Methodology Applied
Scientific EffectAggregation: Coagulation

Implementation Method 2

carbonating them to produce said slag former, preferably by reaction with a gas comprising less than 30 vol. %, preferably less than 25 vol. % and more preferably less than 20 vol. % of carbon dioxide

Methodology Applied
Scientific EffectCarbonation: Chemical Bonding

Implementation Method 3

calcium and/or magnesium carbonates, that is, limestone, dolomite and magnesite, as both slag formers and carbon dioxide sources in the molten slag so as to foam it

Methodology Applied
Scientific EffectDecomposition: Decomposition (biological)

Implementation Method 4

To increase the thermal insulation and refractory lining protection provided by the slag, it has become common to use additives to foam said slag

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 5

incorporating additives like sand and carbonaceous materials to enhance gas permeability and safety

Methodology Applied
Scientific EffectPorosity enhancement: Porosity

Data Source

PatentUS8470067B2Process for preparing a foaming slag former, product and use thereof
Publication Date: 2013.06.25 ORBIX SOLUTIONS
  • US8470067B2 patent drawing
  • US8470067B2 patent drawing
  • US8470067B2 patent drawing

AI summary

Process for preparing a foaming slag former for electric furnaces comprising the steps of aggregating solid slag particles into a coarser granular material and carbonating the solid slag particles to form the foaming slag former. The solid slag particles are preferably aggregated before carbonization, so that the carbonates form a solid matrix binding the particles together.