Metallurgical Slag Treatment Vessel Segmentation

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Solution Overview

Problem

Existing methods for treating metallurgical slags, particularly LD slags from steel production, require high capital and operating costs due to the need for alternating reducing and oxidizing atmospheres, leading to inefficient processes and increased logistics efforts.

Innovation Solution

A method utilizing a divided vessel with separate neutral forehearth, reducing, and oxidizing chambers, allowing independent material transfer and energy management, where high-calorific waste gases from the reduction stage are used for heating in the oxidation phase, and solid LD slag and oxidizers are added for dephosphorization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If alternating reducing and oxidizing treatments are carried out in one and the same vessel, then iron oxide recovery is achieved, but the process complexity and operating costs increase due to constant atmosphere changes

Engineering Contradiction:
Improveiron oxide recoveryVSAvoidprocess complexity
Core Design Contradiction:
Loss of substanceVSDevice complexity

Solution Approach 1:

The treatment vessel is divided into two separate chambers: a reducing chamber for iron oxide reduction and an oxidizing chamber for dephosphorization. This segmentation allows each chamber to maintain a stable, dedicated atmosphere (reducing or oxidizing) without requiring constant switching, thereby reducing process complexity while achieving the same iron oxide recovery goal.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The oxidizing treatment step is extracted from the reducing chamber and performed separately in a dedicated oxidizing chamber. This separation eliminates the need for atmosphere switching in the reducing chamber, simplifying the overall process control while maintaining iron oxide recovery efficiency.

Inventive Principle:
Principle #2Taking out (Extraction)

2Loss of substance

If the metal bath is transported from reducing treatment to oxidizing treatment in a separate ladle, then dephosphorization is achieved, but logistics efforts and operating costs increase

Engineering Contradiction:
ImprovedephosphorizationVSAvoidlogistics effort
Core Design Contradiction:
Loss of substanceVSLoss of time

Solution Approach 1:

The reducing chamber and oxidizing chamber are merged into a single integrated vessel structure with shared heating and control systems. The metal bath remains in the same vessel throughout both treatment steps, eliminating the need for ladle transportation and associated logistics while achieving dephosphorization.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The treatment process continues without interruption as the metal bath transitions directly from reducing to oxidizing atmosphere within the same vessel. This continuous action eliminates downtime associated with ladle transport and repositioning, reducing logistics effort and operating costs.

Inventive Principle:
Principle #20Continuity of useful action

3Reliability

If separate treatment plants are used for reducing and oxidizing treatments, then specialized processing is achieved, but investment costs and logistics increase

Engineering Contradiction:
Improvespecialized processingVSAvoidnumber of treatment plants
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

A single treatment vessel is designed to perform both reducing and oxidizing functions through controlled atmosphere changes. The vessel serves multiple purposes (reduction and dephosphorization) without requiring separate specialized plants, reducing investment costs while maintaining reliable specialized processing in each chamber.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Ease of manufacture

If high-calorific waste gases from reduction stage are not utilized, then process simplicity is maintained, but energy efficiency and operating costs worsen

Engineering Contradiction:
Improveprocess simplicityVSAvoidenergy efficiency
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The high-calorific waste gases produced during the reducing treatment are captured and redirected to fuel the oxidizing chamber. This converts what would be harmful waste emissions into a useful energy source, improving energy efficiency and reducing operating costs while maintaining process simplicity through integrated gas routing.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

Instead of discarding the waste gases from the reduction stage, they are recovered and utilized as fuel for the oxidizing chamber. This recovery process improves energy efficiency by eliminating the need for external fuel sources in the oxidizing stage while maintaining operational simplicity.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach minimizes investment and operating costs while maintaining high output efficiency, enabling continuous operation and efficient use of waste gases, reducing the need for separate treatment plants and logistics.

Implementation Method 1

high-calorific waste gases from the reduction stage are used for heating in the oxidation phase

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 2

efficient use of waste gases, reducing the need for separate treatment plants and logistics

Methodology Applied
Scientific EffectThermal energy transfer: Heat Exchanger

Implementation Method 3

the iron oxide contained in the LD slag is reduced to a metal bath

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 4

a carbon-containing reducing agent is blown in over a longer period of time

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 5

this metal bath is then oxidized Treatment dephosphorized

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 6

a device for the reducing treatment of metallurgical slag is shown, in which the slag is fed from a tiltable feed vessel into a reduction vessel heated by an electric arc

Methodology Applied
Scientific EffectElectric arc heating: Electric Arc

Implementation Method 7

the mixture being electrically heated

Methodology Applied
Scientific EffectInduction heating: Induction Heating

Data Source

PatentEP3375764B1Method for treating metallurgical slag
Publication Date: 2020.01.08 SCHOLZ AUSTRIA GMBH
  • EP3375764B1 patent drawingFigure 1

AI summary

The invention relates to a method for treating metallurgical slags, and in particular slags from steel production, wherein a device (1) is used which is divided into a forehearth (2), a reduction chamber (3), and an oxidation chamber (4), wherein liquid slag, as well as possibly solid agglomerates and residual metal, are filled into the forehearth (2) and kept there at a predetermined temperature, or brought to and kept at this temperature, and the slag and residual steel are left in the forehearth (2) until the reduction chamber (3) is ready to receive material, and subsequently slag and possiblyResidual steel is transferred to the reduction chamber (3) and a reduction is carried out in the reduction chamber (3), whereby the slag is treated with a reducing agent so that metal oxides are reduced and collect at the bottom of a melting plate (9) as molten metal, and the reduced slag is tapped off after reduction and fed to further processing as a hydraulic binder, and the resulting molten metal is fed to the oxidation chamber (4) and is mixed with oxidizing agents and oxidized in the oxidation chamber (4) in order to remove accompanying metals from the molten metal and bind them in a slag present in the oxidation chamber (4), as well as a device for this purpose.