Sliding Element Coating with Layered DLC Structure

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing sliding elements, such as piston rings, face challenges in achieving a balance between low friction and wear resistance, as DLC coatings with layer thicknesses above or below 5 μm alter their properties, and PVD coatings based on hard materials like chromium nitride do not adequately reduce friction while maintaining wear resistance.

Innovation Solution

A sliding element with a coating structure from the inside outwards comprising an adhesive layer, a metal-containing DLC layer with tungsten, and a metal-free DLC layer, where the thickness ratio between the metal-free and metal-containing layers is between 0.7 and 1.5, and the top layer to total layer ratio is between 0.4 and 0.6, optimized for amorphous carbon composition and nanocrystalline tungsten carbide precipitates, ensuring balanced tribological properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If DLC coating layer thickness is increased above 5 μm, then wear resistance is improved, but layer properties alter (structure and composition) such that service life is not achieved

Engineering Contradiction:
Improvewear resistanceVSAvoidlayer structure and composition
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The coating is divided into multiple functional layers: an adhesive layer for substrate bonding, a metal-containing DLC layer (with tungsten) for stress compensation and wear resistance, and a metal-free DLC layer for low friction. This segmentation allows each layer to optimize its specific function while maintaining overall coating stability and performance.

Inventive Principle:
Principle #1Segmentation

2Stability of the object's composition

If DLC coating layer thickness is decreased below 5 μm, then coating uniformity is improved, but wear resistance is insufficient

Engineering Contradiction:
Improvecoating uniformityVSAvoidwear resistance
Core Design Contradiction:
Stability of the object's compositionVSStrength

Solution Approach 1:

The coating uses composite material structures combining different DLC types (metal-containing and metal-free) with an adhesive layer. The metal-containing DLC layer provides wear resistance and stress management, while the metal-free DLC layer maintains low friction, creating a composite system that achieves both uniformity and adequate wear protection.

Inventive Principle:
Principle #40Composite materials

3Strength

If PVD coating based on hard material (chromium nitride) is used, then wear resistance is achieved, but coefficient of friction is not sufficiently reduced

Engineering Contradiction:
Improvewear resistanceVSAvoidcoefficient of friction
Core Design Contradiction:
StrengthVSUse of energy by moving object

Solution Approach 1:

The invention changes the material parameters by using DLC (diamond-like carbon) instead of traditional PVD chromium nitride coatings. DLC provides inherently lower friction coefficients while maintaining wear resistance. The addition of metal elements (particularly tungsten) in the DLC layer further modifies the tribological parameters to achieve optimal friction and wear performance.

Inventive Principle:
Principle #35Parameter changes

4Use of energy by moving object

If top layer (metal-free DLC) is made thicker to improve friction properties, then coefficient of friction is reduced, but wear values become worse

Engineering Contradiction:
Improvecoefficient of frictionVSAvoidwear resistance
Core Design Contradiction:
Use of energy by moving objectVSStrength

Solution Approach 1:

Different regions of the coating have different properties optimized for their specific functions. The metal-free DLC top layer provides low friction where it contacts the counterface, while the metal-containing DLC intermediate layer provides wear resistance and stress compensation. This local quality differentiation allows the coating to achieve both low friction and good wear resistance simultaneously.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating achieves significantly reduced wear and constant low friction coefficients, enhancing the service life of sliding elements by compensating internal stresses and maintaining optimal strength and toughness, particularly when the middle and top layers have similar thicknesses, thereby improving durability and performance in internal combustion engines.

Implementation Method 1

the metal-free DLC layer first introduces into the overall system, i.e. into the coating as a whole, very high internal stresses that, in the case of the metal-containing DLC layer being of a layer thickness similar to the thickness of the outermost layer, can be compensated in such a way that the coating is realised in an optimal manner with regard to the combination between strength and toughness

Methodology Applied
Scientific EffectStress compensation: Stress Relaxation

Implementation Method 2

the friction, which is directly associated with the fuel consumption in the case of internal combustion engines, can be kept to a low level by coatings of DLC (diamond-like carbon)

Methodology Applied
Scientific EffectLow friction coefficient: Friction

Implementation Method 3

Although such layers do have the necessary resistance to wear, they nevertheless do not have the required low coefficients of friction

Methodology Applied
Scientific EffectWear resistance: Wear

Data Source

PatentUS9611543B2Sliding element having a coating
Publication Date: 2017.04.04 FEDERAL MOGUL BURSCHEID GMBH
  • US9611543B2 patent drawing
  • US9611543B2 patent drawing
  • US9611543B2 patent drawing

AI summary

The invention relates to a sliding element, such as a piston ring, having a coating on at least one running surface, which comprises, from the inside out, an adhesive layer (10), a metal-containing, preferably tungsten-containing, DLC layer (12), and a metal-free DLC layer (14), and is characterized in that the ratio of the thickness of the metal-free DLC layer to the thickness of the metal-containing DLC layer ranges from 0.7 to 1.5 and/or to the overall thickness of the coating ranges from 0.4 to 0.6.