Sludge Dewaterability via Pre-Fermentation and Thermal Hydrolysis

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Solution Overview

Problem

The presence of phosphorus, ammonia, and magnesium in sludge makes dewatering difficult and increases the potential for struvite formation and ammonia toxicity during anaerobic digestion, leading to reduced dry solids content and increased polymer doses, as well as struvite scaling issues in wastewater treatment processes.

Innovation Solution

Pre-treating sludge by controlling temperature and hydraulic retention time in a biological fermenter to release phosphorus and ammonia, followed by pre-dewatering and subsequent thermal hydrolysis, which allows for the recovery and utilization of these components to form struvite, thereby improving dewaterability and reducing struvite formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If sludge is subjected to anaerobic digestion, then phosphorus is released from biomass as orthophosphate, but dewaterability deteriorates due to high PO4 concentration and shifted cation ratio

Engineering Contradiction:
Improvephosphorus releaseVSAvoiddewaterability
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent applies preliminary action by conducting a pre-fermentation step before anaerobic digestion to release phosphorus, ammonia and magnesium from biomass. This preliminary release allows these components to be removed via pre-dewatering, preventing their negative impact on subsequent dewatering operations. The pre-fermentation is controlled to optimize component release while maintaining biomass integrity for later digestion.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent segments the sludge treatment process into distinct stages: pre-fermentation in a biological fermenter, pre-dewatering in a solids-liquid separator, thermal hydrolysis, and anaerobic digestion. This segmentation allows phosphorus and other components to be released and removed before the main digestion process, eliminating the contradiction between phosphorus release and dewaterability.

Inventive Principle:
Principle #1Segmentation

2Quantity of substance

If sludge contains phosphorus, ammonia and magnesium, then struvite formation potential increases, but this causes scaling issues in pipes and conduits

Engineering Contradiction:
Improvestruvite formation potentialVSAvoidstruvite scaling
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent extracts phosphorus, ammonia and magnesium from the sludge matrix through controlled pre-fermentation and removes them via pre-dewatering. By taking out these components before they can react to form struvite, the process eliminates the source material needed for struvite scaling in pipes and conduits, while the extracted components can be separately managed or recovered.

Inventive Principle:
Principle #2Taking out (Extraction)

3Quantity of substance

If thermal hydrolysis is performed, then high ammonia concentrations are released, but this reaches inhibiting levels in the anaerobic digester

Engineering Contradiction:
Improveammonia releaseVSAvoidammonia toxicity
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary action by releasing ammonia during the pre-fermentation stage before thermal hydrolysis and anaerobic digestion. This allows ammonia to be partially removed via pre-dewatering, reducing the total ammonia load that would otherwise be released during thermal hydrolysis and potentially inhibit the anaerobic digester.

Inventive Principle:
Principle #10Preliminary action

4Productivity

If polymer dose is increased to maintain dewatering performance, then treatment effectiveness is maintained, but operational cost increases

Engineering Contradiction:
Improvedewatering performanceVSAvoidpolymer dose
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent applies preliminary action by removing phosphorus, ammonia and magnesium through pre-fermentation and pre-dewatering before the main dewatering step. This preliminary removal of dewatering-inhibiting components allows subsequent dewatering to achieve high performance with reduced polymer dosage, as the sludge matrix is already conditioned and less resistant to water removal.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process enhances dewaterability, reduces struvite formation and ammonia toxicity, and minimizes phosphorus in landfills, while potentially decreasing reactor and storage system requirements, and improving overall dewatering performance.

Implementation Method 1

Sludge is directed to a biological fermenter and by controlling the temperature of the sludge and/or the hydraulic retention time of the sludge in the fermenter, phosphorus and ammonia is released from the biomass in the sludge

Methodology Applied
Scientific EffectBiological fermentation: Fermentation

Implementation Method 2

The concentrated sludge is then directed to a thermal hydrolysis reactor and undergoes thermal hydrolysis

Methodology Applied
Scientific EffectThermal hydrolysis: Hydrolysis

Implementation Method 3

the thermally hydrolyzed sludge is directed to an anaerobic digester and subjected to anaerobic digestion

Methodology Applied
Scientific EffectAnaerobic digestion: Anaerobic Digestion

Implementation Method 4

the sludge is directed to a solids-liquid separation or pre-dewatering device which yields a concentrated sludge and a liquid stream rich in phosphorus, ammonia and magnesium

Methodology Applied
Scientific EffectPhysical separation: Sedimentation

Data Source

PatentEP3728141B1Method of treating sludge
Publication Date: 2024.05.08 VEOLIA WATER SOLUTIONS & TECHNOLOGIES SUPPORT SAS
  • EP3728141B1 patent drawingFigure 1

AI summary

The present invention relates to a method of treating sludge containing phosphorus, ammonia and magnesium and enhancing the dewaterability of the sludge. The sludge is directed into a biological fermenter operated under anaerobic conditions. By controlling the temperature of the sludge in the fermenter or the hydraulic retention time of the sludge in the fermenter, phosphorus, ammonia and magnesium is released from the solids in the sludge into a liquid forming a part of the sludge. Sludge from the fermenter is subjected to a solids-liquid separation process that produces a concentrated sludge and a liquid. The concentrated sludge or separated solids is directed to a thermal hydrolysis reactor that thermally hydrolyzes the concentrated sludge. After thermally hydrolyzing the concentrated sludge, the concentrated sludge is directed to an anaerobic digester that anaerobically digests the concentrated sludge.