Sludge Solid-Liquid Interface Renewal for Methane Production

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Solution Overview

Problem

Anaerobic sludge digestion has low efficiency due to limitations in hydrolysis and biodegradability of organic matter, with existing pretreatment methods often causing more harm and reducing biodegradability, leading to suboptimal methane production.

Innovation Solution

A method involving centrifugation, thermal baking, and redissolution in softened water to renew the solid-liquid interface in sludge, altering its physical structure and enhancing biodegradability, thereby increasing methane production through anaerobic biotransformation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If traditional pretreatment methods (hydrothermal, alkaline, microwave) are used to enhance organic matter dissolution, then the dissolution degree of organic matter is improved, but the biodegradability of organic matter is reduced due to formation of hard-to-degrade molecules

Engineering Contradiction:
Improvedissolution degree of organic matterVSAvoidbiodegradability of organic matter
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent changes the physical-chemical parameters of the solid-liquid interface through controlled thermal treatment and pH adjustment, transforming the interface properties to enhance both dissolution and biodegradability simultaneously. This resolves the contradiction by finding optimal parameter ranges where organic matter dissolves effectively without forming recalcitrant compounds.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies localized treatment to the solid-liquid interface region specifically, using targeted enzymatic additives and localized thermal fields to modify only the interfacial properties. This selective local modification enhances dissolution at the interface while preserving the bulk organic matter's biodegradability, avoiding the formation of hard-to-degrade molecules throughout the entire system.

Inventive Principle:
Principle #3Local quality

2Quantity of substance

If high temperature hydrothermal treatment is applied to pretreatment, then organic matter dissolution is enhanced, but polycondensation of micromolecular organic matter occurs producing macromolecules that increase degradation difficulty

Engineering Contradiction:
Improveorganic matter dissolutionVSAvoidpolycondensation reaction control
Core Design Contradiction:
Quantity of substanceVSTemperature

Solution Approach 1:

The patent applies preliminary mild thermal treatment and pH adjustment before the main hydrothermal process to pre-modify the organic matter structure. This preliminary action prepares the organic matter for subsequent dissolution without triggering excessive polycondensation, thereby preventing the formation of difficult-to-degrade macromolecules while still achieving effective dissolution.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces intermediary substances such as enzymes or chemical catalysts that mediate the hydrothermal process. These intermediaries facilitate organic matter dissolution at lower temperatures by breaking down complex structures selectively, preventing the temperature from reaching levels that would cause unwanted polycondensation and macromolecule formation.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If conventional anaerobic digestion is used, then sludge treatment is performed, but methane production efficiency is low with removal rate of organic matter less than 50%

Engineering Contradiction:
Improvemethane production efficiencyVSAvoidorganic matter removal rate
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent replaces the purely biological mechanical system of conventional anaerobic digestion with a hybrid system that incorporates physical-chemical pretreatment steps. By substituting part of the biological process with controlled physical-chemical interface renewal, the system achieves better organic matter breakdown before anaerobic digestion, thereby increasing both methane production efficiency and organic matter removal rate.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method significantly increases methane production from organic matter by 50% to 200% by reducing energy barriers and improving electron utilization efficiency during anaerobic digestion, enhancing the overall efficiency of sludge treatment.

Implementation Method 1

subjecting sludge to a centrifugation, a thermal baking and a redissolution in softened water in sequence to renew a solid-liquid interface in the sludge

Methodology Applied
Scientific EffectCentrifugal force: Centrifugal Force

Implementation Method 2

subjecting sludge to a centrifugation, a thermal baking and a redissolution in softened water in sequence to renew a solid-liquid interface in the sludge

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 3

subjecting sludge to a centrifugation, a thermal baking and a redissolution in softened water in sequence to renew a solid-liquid interface in the sludge

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 4

subjecting the sludge to an anaerobic digestion to increase methane production from organic matter in the sludge by anaerobic biotransformation

Methodology Applied
Scientific EffectAnaerobic biotransformation: Anaerobic Digestion

Data Source

PatentUS11834359B2Method for enhancing anaerobic digestion based on solid-liquid interface renewal in sludge
Publication Date: 2023.12.05 SHANGHAI URBAN POLLUTION CONTROL ENG RES CENT CO LTD
  • US11834359B2 patent drawing

AI summary

A method for enhancing anaerobic digestion based on solid-liquid interface renewal in sludge is disclosed. The method includes subjecting sludge to a centrifugation, a thermal baking and a redissolution in softened water in sequence to renew a solid-liquid interface in sludge, and subjecting the sludge to an anaerobic digestion to increase methane production from organic matter in the sludge by anaerobic biotransformation.