Putrescible Sludge Cake Stabilization via Anoxic Nitrate Reduction

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Solution Overview

Problem

Current methods for treating putrescible sewage sludge cakes, such as incineration, land filling, and chemical treatments, are environmentally harmful, costly, and inefficient in reducing E. coli and odour, with existing processes being slow, energy-intensive, or ineffective in maintaining stability and preventing odour release.

Innovation Solution

Maintaining the sludge cake under anoxic conditions with a nitrate moiety, preferably in the presence of ammonium compounds, to reduce E. coli and odour, and optionally adjusting pH and incorporating a bulking agent to improve handling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If biological processes such as anaerobic digestion or composting are used to treat sewage sludge, then stability is imparted to the waste by reducing organic content, but the processes are very slow and require costly processing plants

Engineering Contradiction:
ImprovestabilityVSAvoidtime
Core Design Contradiction:
Stability of the object's compositionVSLoss of time

Solution Approach 1:

The invention changes the chemical parameters of the sludge by adding lime to raise the pH to above 12, which rapidly deactivates pathogens and stabilizes the waste without requiring long biological digestion periods. This chemical parameter change achieves stability much faster than biological processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the slow biological mechanical process of anaerobic digestion or composting with a rapid chemical process using lime. This substitution eliminates the need for lengthy biological treatment while achieving the same stability and pathogen reduction goals.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Stability of the object's composition

If thermal drying is used to treat sewage sludge, then stability is achieved by reducing water content below 10%, but the process is very energy intensive and hazardous due to explosion risk with dust

Engineering Contradiction:
ImprovestabilityVSAvoidenergy
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by moving object

Solution Approach 1:

The invention replaces the energy-intensive thermal drying process with a chemical stabilization process using lime. Instead of removing water through high-energy heating, the lime chemically stabilizes the sludge at lower temperatures, eliminating the explosion hazard while reducing energy consumption.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention uses lime, a cheap and readily available material, to achieve rapid stabilization without requiring expensive energy-intensive drying equipment or facilities. The lime provides immediate pathogen deactivation and stability at low cost.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If lime treatment is used to treat sewage sludge, then pathogens such as E. coli are deactivated by raising pH to over 12, but on exposure to air during long stockpiling, reaction between lime and carbon dioxide rapidly reduces pH where biological activities can resume and odour release may cause nuisance

Engineering Contradiction:
Improvepathogen deactivationVSAvoidpH stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The invention applies lime treatment immediately upon receipt of the sludge, performing the pathogen deactivation action before the sludge can be exposed to air and undergo pH reduction from carbon dioxide reaction. This preliminary action ensures pathogens are deactivated before stability issues can arise.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention maintains the high pH condition continuously by applying lime and preventing contact with carbon dioxide-rich air during storage. This continuous maintenance of alkaline conditions prevents the pH drop that would allow biological activity and odour generation to resume.

Inventive Principle:
Principle #20Continuity of useful action

4Ease of manufacture

If incineration or land filling are used to dispose of organic wastes, then waste is disposed off, but these methods are regarded as needless destruction of valuable resources and environmentally harmful

Engineering Contradiction:
Improvewaste disposalVSAvoidenvironmental harm
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The invention converts the harmful effect of sewage sludge (odour and pathogen contamination) into a beneficial stabilized product suitable for agricultural reuse. By rapidly deactivating pathogens and stabilizing the sludge through lime treatment, the waste transforms from a harmful substance into a safe agricultural fertilizer, eliminating the need for incineration or land filling.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The invention recovers the valuable nutrients in sewage sludge for agricultural use rather than discarding them through incineration or land filling. The lime treatment enables safe recovery and reuse of the sludge as fertilizer, transforming a waste disposal problem into a resource recovery opportunity.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively reduces E. coli and odour in putrescible cakes, preventing further odour generation, and stabilizes the material for safe recycling, as demonstrated by significant reductions in E. coli counts and odour neutralization across various examples.

Implementation Method 1

maintaining the cake under substantially anoxic condition in the presence of a nitrate moiety

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 2

maintaining the cake under substantially anoxic condition in the presence of both ammonium and nitrate moieties

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS7504035B2Treatment of putrescrible cakes
Publication Date: 2009.03.17 UNITED UTILITIES

AI summary

A method of treating putrescible cakes to reduce the E. Coli and odor present in the cake and prevent further odor generation comprising the step of maintaining the cake under substantially anoxic condition in the presence of ammonium and/or nitrate moieties at pH 7.5 to pH 10.5 for a period of more than 1 day, the cake having a solids content of between 20% to 75% by weight.