Smectic Liquid Crystal Polarizer Alignment and Light Fastness

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Solution Overview

Problem

Existing polarizers face challenges in achieving both high degree of alignment and light fastness, as they often require specific production processes for each function and are limited by the type of polymerizable liquid crystal used and polymerization conditions.

Innovation Solution

A polarizer formed from a composition containing a polymer compound with smectic liquid crystallinity, having a weight-average molecular weight of 3000 or greater, and optionally with nematic liquid crystallinity, and a dichroic material concentration of 5% or greater, which is aligned and cooled to achieve both alignment and light fastness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a polymerizable liquid crystal is used as a host material in a guest-host polarizer, then the polarizer can achieve polarization function, but it is difficult to achieve both high degree of alignment and light fastness simultaneously

Engineering Contradiction:
Improvedegree of alignmentVSAvoidlight fastness
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the molecular weight parameter of the liquid crystal compound to 3000 or greater, which fundamentally alters the material properties. This parameter change enables the liquid crystal to maintain both high alignment degree (29 improvement) and light fastness (27 improvement) simultaneously, resolving the technical contradiction between manufacturing precision and reliability.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If different production processes are used for each function (attenuation, polarization, scattering, light shielding), then each function can be optimized, but the device complexity and production complexity increase

Engineering Contradiction:
Improvefunctional performanceVSAvoidproduction process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent creates a universal polarizer composition that can simultaneously achieve multiple functions including polarization, light shielding, and scattering. By using a polymer compound with smectic liquid crystallinity combined with dichroic materials, the invention enables a single device to perform multiple optical functions that previously required separate production processes, thereby reducing device complexity while maintaining functional performance.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges previously separate functional components into a single integrated polarizer system. The combination of polymer compound with smectic liquid crystallinity and dichroic materials creates a unified structure that performs multiple functions simultaneously, eliminating the need for separate devices for attenuation, polarization, scattering, and light shielding.

Inventive Principle:
Principle #5Merging (Combining)

3Reliability

If the concentration of dichroic material is increased to improve light fastness, then polarization durability improves, but the manufacturing precision and alignment quality may deteriorate

Engineering Contradiction:
Improvelight fastnessVSAvoidalignment quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the fundamental parameter of the liquid crystal compound (molecular weight ≥3000 and smectic liquid crystallinity) which allows the system to tolerate higher dichroic material concentrations without compromising alignment quality. This parameter change decouples the trade-off between light fastness and alignment quality, enabling both to be improved simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables the achievement of both high degree of alignment and light fastness in polarizers, enhancing their heat resistance and stability while simplifying the production process.

Implementation Method 1

the liquid crystal compound is a polymer compound having a smectic liquid crystallinity

Methodology Applied
Scientific EffectSmectic liquid crystallinity: Liquid Crystals

Implementation Method 2

a cooling step of cooling the coating film to a temperature range of 20° C. to 25° C. at a cooling rate of 3° C./sec or greater from the liquid crystal state

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS11953775B2Polarizer, method of producing polarizer, laminate, and image display device
Publication Date: 2024.04.09 FUJIFILM CORP
  • US11953775B2 patent drawing
  • US11953775B2 patent drawing
  • US11953775B2 patent drawing

AI summary

An object of the present invention is to provide a polarizer, a method of producing a polarizer, a laminate, and an image display device which enable achievement of both the degree of alignment and light fastness. The polarizer of the present invention is a polarizer formed of a polarizer-forming composition which contains a liquid crystal compound and a dichroic material, in which the liquid crystal compound is a polymer compound having a smectic liquid crystallinity.