SOC Estimation for Blended Cathode Batteries

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Solution Overview

Problem

Existing secondary battery technologies face challenges in accurately estimating the State of Charge (SOC) of lithium secondary batteries, particularly when using blended cathode materials, due to unusual voltage behaviors in transition regions, leading to increased estimation errors during repeated charging and discharging cycles in hybrid electric vehicle modes.

Innovation Solution

A method and apparatus that utilize a blended cathode material with different operating voltage ranges, incorporating a sensor to measure dynamic voltage and a control unit to identify transition region voltage patterns, calculate parameters, and estimate SOC using a predetermined relationship, such as a look-up table or function, to accurately determine the SOC even in transition regions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a blended cathode material is used to improve battery performance, then energy capacity and stability are improved, but voltage behavior becomes unusual in transition regions leading to increased SOC estimation error

Engineering Contradiction:
Improvebattery performanceVSAvoidSOC estimation accuracy
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The voltage range of the blended cathode material is segmented into multiple regions (first voltage range, second voltage range, and transition region between them). Each region corresponds to different active cathode materials, allowing the system to identify which region is currently active and apply appropriate SOC estimation methods for each region, thereby resolving the measurement accuracy issue in transition regions

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system changes the parameter used for SOC estimation based on the voltage region. In non-transition regions, conventional voltage-SOC relationships are used, while in transition regions, the system identifies the unusual voltage behavior and applies corrected estimation methods, effectively adapting the estimation parameter to the current operating condition

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If conventional SOC estimation methods are used, then the system is simple to operate, but estimation error increases in transition regions with distinctive voltage behaviors

Engineering Contradiction:
ImproveSOC estimation simplicityVSAvoidSOC estimation accuracy
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The system continuously monitors the voltage-SOC relationship and identifies when the battery enters a transition region by detecting unusual voltage behaviors. This feedback mechanism triggers a switch from conventional estimation methods to region-specific estimation methods, maintaining both simplicity and accuracy by only applying complex methods when necessary

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system pre-establishes multiple voltage-SOC relationship models corresponding to different voltage regions and cathode materials. Before SOC estimation, the system determines which region is currently active and selects the appropriate pre-prepared model, avoiding real-time complex calculations while ensuring accuracy for the current operating condition

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for reliable SOC estimation in secondary batteries with blended cathode materials, reducing estimation errors and improving accuracy even in regions with distinctive voltage behaviors, thus enhancing the performance and reliability of electric vehicles operating in hybrid electric vehicle modes.

Implementation Method 1

a sensor configured to measure a dynamic voltage of the secondary battery during charging of the secondary battery

Methodology Applied
Scientific EffectVoltage measurement: Electric Field

Implementation Method 2

A battery generates electric energy by oxidation and reduction reactions

Methodology Applied
Scientific EffectElectrochemical reaction: Redox Reactions

Implementation Method 3

a control unit configured to identify a dynamic voltage profile of the secondary battery as a transition region voltage pattern, calculate a parameter of the transition region voltage pattern, and estimate a SOC of the secondary battery from the calculated parameter

Methodology Applied
Scientific EffectVoltage pattern recognition:

Data Source

PatentEP3901642B1Apparatus and method for estimating SOC of secondary battery including blended cathode material
Publication Date: 2022.09.14 LG ENERGY SOLUTION LTD
  • EP3901642B1 patent drawingFigure 1~2
  • EP3901642B1 patent drawingFigure 3~4
  • EP3901642B1 patent drawingFigure 5~6

AI summary

Disclosed is an apparatus for estimating a state of charge (SOC) of a secondary battery which includes (i) a cathode comprising a blended cathode material having a first cathode material and a second cathode material, wherein the first and second cathode materials have different operating voltage ranges; (ii) an anode comprising an anode material; and (iii) a separator for separating the cathode from the anode. The apparatus includes a sensor configured to measure a dynamic voltage of the secondary battery during charging of the secondary battery, and a control unit configured to identify a dynamic voltage profile of the secondary battery as a transition region voltage pattern, calculate a parameter of the transition region voltage pattern, and estimate a SOC of the secondary battery from the calculated parameter by using a predetermined relationship between the parameter and the SOC.