Sodium Halide Nanocomposite Electrolyte for Stable Ion Conduction

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Solution Overview

Problem

Existing lithium ion batteries face issues with low thermal stability, ignitability, and leakage due to organic liquid electrolytes, and sulfide-based solid electrolytes have limitations in electrochemical and atmospheric stability, making them unsuitable for large-scale energy storage applications, particularly in electric vehicles.

Innovation Solution

A sodium halide-based nanocomposite is developed, where a nanosized compound is dispersed in a halide compound to enhance ionic conductivity and interfacial stability, forming a glass-ceramic crystal structure that improves the performance of all-solid-state batteries by activating an interfacial conduction phenomenon.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If sulfide-based solid electrolytes are used, then ionic conductivity is improved, but electrochemical stability and atmospheric stability deteriorate

Engineering Contradiction:
Improveionic conductivityVSAvoidelectrochemical stability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent uses a composite structure consisting of a sulfide-based solid electrolyte core and an oxide-based coating layer. The sulfide core provides high ionic conductivity while the oxide coating layer provides electrochemical stability and atmospheric stability. This composite approach allows both requirements to be satisfied simultaneously by assigning different functions to different components of the system.

Inventive Principle:
Principle #40Composite materials

2Reliability

If oxide-based solid electrolytes are used, then electrochemical stability is improved, but ionic conductivity deteriorates

Engineering Contradiction:
Improveelectrochemical stabilityVSAvoidionic conductivity
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent creates a composite material where the oxide-based coating layer is applied on the surface of the sulfide-based solid electrolyte. The bulk sulfide material maintains high ionic conductivity while the surface oxide layer provides the required electrochemical stability. This spatial separation of functions resolves the contradiction between stability and conductivity.

Inventive Principle:
Principle #40Composite materials

3Use of energy by moving object

If central metal or anion substitution is used in halide-based solid electrolytes, then ionic conductivity is improved, but there is still a limit to reaching sulfide-based material levels

Engineering Contradiction:
Improveionic conductivityVSAvoidmanufacturing complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

Instead of attempting to improve halide-based electrolytes through complex substitution methods, the patent adopts a simpler composite approach: combining sulfide-based electrolyte (for high conductivity) with oxide-based coating (for stability). This composite strategy achieves the desired performance level more directly without requiring complex manufacturing processes.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sodium halide-based nanocomposite significantly improves ionic conductivity and high-potential cycle stability, reducing the risk of side reactions and enhancing the overall performance of all-solid-state batteries, making them more suitable for large-scale energy storage applications.

Implementation Method 1

a nanosized compound selected from M1Oc, NaX, and a combination thereof is dispersed in a halide compound... to enhance ionic conductivity and interfacial stability, forming a glass-ceramic crystal structure that improves the performance of all-solid-state batteries by activating an interfacial conduction phenomenon

Methodology Applied
Scientific EffectInterfacial conduction: Conduction (electrical)

Data Source

PatentUS20230411616A1Sodium Halide-based Nanocomposite, Preparing Method Thereof, and Positive Electrode Active Material, Solid Electrolyte, and All-solid-state Battery Comprising the Same
Publication Date: 2023.12.21 UI (UNIVERSITY IND FOUNDATION) YONSEI UNIVERSITY
  • US20230411616A1 patent drawing
  • US20230411616A1 patent drawing
  • US20230411616A1 patent drawing

AI summary

Disclosed are a sodium halide-based nanocomposite, a method of preparing the same, a solid electrolyte including the sodium halide-based nanocomposite, and an all-solid-state battery including the solid electrolyte, the sodium halide-based nanocomposite including a nanosized compound selected from M1Oc, NaX, or and a combination thereof dispersed in a halide compound.