Sodium Hexatitanate Friction Modifier for Wide-Temperature Braking

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Solution Overview

Problem

Friction materials containing potassium titanate fibers exhibit low friction coefficients at low temperatures and lack sufficient wear resistance, particularly at high temperatures, necessitating a friction modifier that can enhance friction and wear resistance across a wide temperature range.

Innovation Solution

Sodium hexatitanate with a novel indeterminate shape and specific surface area, produced through mechanochemical milling and firing of titanium and sodium sources, is used as a friction modifier, offering superior wear resistance and reinforcing performance in resin compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If potassium titanate fibers are used as friction modifier, then sliding property and braking effect are improved, but friction coefficient at low temperature decreases and wear resistance at high temperature is insufficient

Engineering Contradiction:
Improvebraking effectVSAvoidfriction coefficient at low temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The invention changes the chemical composition parameter by substituting potassium titanate with sodium hexatitanate, which has different frictional properties. This compositional parameter change enables the friction material to maintain high friction coefficients across both low and high temperature ranges, resolving the temperature-dependent friction coefficient problem

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite friction materials containing sodium hexatitanate combined with other friction material components. This composite approach leverages the superior high-temperature wear resistance of sodium hexatitanate while maintaining overall braking performance, addressing both the low-temperature friction issue and high-temperature wear resistance

Inventive Principle:
Principle #40Composite materials

2Reliability

If potassium titanate fibers are used as friction modifier, then braking effect is improved, but wear resistance at high temperature is insufficient

Engineering Contradiction:
Improvebraking effectVSAvoidwear resistance
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The invention changes the material composition parameter by using sodium hexatitanate instead of potassium titanate. Sodium hexatitanate possesses superior high-temperature stability and wear resistance properties, which directly address the insufficient wear resistance at high temperatures while maintaining effective braking performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs sodium hexatitanate particles that can be readily replaced or replenished in the friction material matrix. These particles provide durable wear resistance during high-temperature operation, extending the service life of the friction material without compromising braking effect

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sodium hexatitanate provides stable friction and wear characteristics over a low to high temperature range, effectively improving the braking performance and service life of friction materials in various applications.

Implementation Method 1

mechanochemical milling of a titanium source and a sodium source

Methodology Applied
Scientific EffectMechanochemical milling:

Implementation Method 2

firing the milled mixture

Methodology Applied
Scientific EffectFiring:

Implementation Method 3

an acid treatment that dissolves a sodium content

Methodology Applied
Scientific EffectAcid treatment dissolution:

Data Source

PatentUS8877339B2Sodium hexatitanate and method for production thereof
Publication Date: 2014.11.04 OTSUKA CHEMICAL CO LTD
  • US8877339B2 patent drawing
  • US8877339B2 patent drawing
  • US8877339B2 patent drawing

AI summary

Sodium hexatitanate having a mean particle diameter in the range of 2-5 μm and an indeterminate shape, and is either obtained by firing a milled mixture obtained as a result of mechanochemical milling of a titanium source and a sodium source or prepared from sodium trititanate obtained by firing a milled mixture obtained as a result of mechanochemical milling of a titanium source and a sodium source.