SOEC-SOFC Stack Bypass Control for Temperature and Pressure Stability

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Solution Overview

Problem

Current technologies lack a satisfactory solution for managing both thermal and internal pressure regulation within a reversible solid oxide electrochemical cell stack, which operates either as a SOFC fuel cell or a SOEC electrolyzer, leading to challenges in maintaining consistent hydrogen production and thermal stability.

Innovation Solution

A system with a bypass line and adjustable valves is implemented to divert hot gases from the oxygen chambers, allowing for simultaneous reduction of temperature and pressure within the stack, along with additional heat exchangers to preheat gases and manage pressure differences between hydrogen and oxygen chambers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If a bypass line with adjustable valve is implemented to divert hot gases from oxygen chambers, then temperature and pressure within the stack are regulated, but device complexity increases

Engineering Contradiction:
Improvestack temperatureVSAvoidsystem complexity
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The gas flow path is segmented into two separate paths: a main path through the heat exchanger and a bypass path with an adjustable valve. This segmentation allows independent control of temperature and pressure by directing different proportions of hot gases through each path, resolving the contradiction by adding control flexibility without requiring complete system redesign.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The bypass line acts as an intermediary pathway that mediates between the heat exchanger and the oxygen chambers. By introducing this intermediate flow path with an adjustable valve, the system can fine-tune temperature and pressure independently, managing the complexity through a dedicated control mechanism rather than modifying the entire system.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Use of energy by moving object

If additional heat exchangers are added to preheat gases and manage pressure differences, then energy efficiency is improved, but device complexity increases

Engineering Contradiction:
Improveenergy efficiencyVSAvoidsystem complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The heat exchanger serves multiple functions simultaneously: it preheats the gases entering the oxygen chambers, manages pressure differences between hydrogen and oxygen chambers, and recovers heat from hot gases. By merging these functions into a single component, the system improves energy efficiency without proportionally increasing complexity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The heat exchanger is designed as a multi-functional component that performs thermal preheating, pressure balancing, and heat recovery operations. This universal approach allows one component to address multiple technical requirements, improving energy efficiency while limiting the increase in device complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Stability of the object's composition

If hot gases are diverted from oxygen chambers, then thermal stability is improved, but loss of useful heat energy occurs

Engineering Contradiction:
Improvethermal stabilityVSAvoidheat energy loss
Core Design Contradiction:
Stability of the object's compositionVSLoss of energy

Solution Approach 1:

The bypass line, which could be seen as diverting useful heat away from the oxygen chambers, actually converts potential heat loss into a beneficial thermal stability control mechanism. The adjustable valve allows precise control of heat distribution, converting the potential harm of heat diversion into the benefit of stable temperature management.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

By changing the flow distribution parameter through the adjustable valve on the bypass line, the system optimizes the balance between thermal stability and heat energy utilization. The valve allows dynamic adjustment of the proportion of hot gases diverted, enabling the system to adapt to different operational requirements and minimize energy loss while maintaining thermal stability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively regulates both temperature and pressure within the stack, improving energy efficiency and maintaining stable operation across different modes of operation, particularly when switching between SOEC electrolysis and SOFC fuel cell modes.

Implementation Method 1

a first heat exchanger, arranged between the second supply line and the second exhaust line, so as to recover the heat from the gases exiting the second chambers and transfer it to the gases entering these same chambers in order to preheat said gases

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

a bypass line of the second exhaust line, arranged between the inlet and outlet of the exchanger, so as to divert all or part of the gases from the outlet of the second chambers

Methodology Applied
Scientific EffectGas flow diversion:

Implementation Method 3

a flow control valve, suitable for allowing a flow rate from 0 to 100%, arranged on the bypass line

Methodology Applied
Scientific EffectFlow control: Valve

Data Source

PatentEP3494608B1System for controlling the temperature and pressure of a high temperature electrolyser (SOEC) reversibly operable as fuel cell (SOFC)
Publication Date: 2023.10.11 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP3494608B1 patent drawingFigure 1~2
  • EP3494608B1 patent drawingFigure 3~4
  • EP3494608B1 patent drawingFigure 5~6

AI summary

The invention relates to a system able to operate reversibly as an SOFC fuel-cell stack or as an SOEC electrolyser. According to the invention, a bypass line or circuit is provided in order to divert if needs be some of the hot gases issued from the chambers referred to as oxygen chambers (anodic chambers in SOEC mode, cathodic chambers in SOFC-stack mode) as this will cool the heat exchanger provided in the circuit through which the oxygen flows.