Decoupled Compressive Force Seal for High-Pressure SOFC Modules

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Solution Overview

Problem

High-temperature solid-oxide fuel cells (SOFC) and electrolyzers face challenges in maintaining leak-tightness and efficient gas distribution under pressure, as conventional glass or glass-ceramic seals are prone to failure at high pressures and temperatures, requiring complex and costly pressurized chambers for operation.

Innovation Solution

A module design with a compression piston and sealing bellows that decouples the forces for compressing seals from those for electrical contact, using adjustable compressive forces and a sealing bellows to manage pressure and ensure leak-tightness without a pressurized chamber, and incorporating mica seals for enhanced adhesion and mechanical integrity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional glass or glass-ceramic seals are used in high-temperature solid-oxide fuel cells and electrolyzers, then electrical insulation and basic sealing are achieved, but leak-tightness fails under high pressure and temperature conditions

Engineering Contradiction:
Improveleak-tightnessVSAvoidoperating temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent changes the material parameter from conventional glass/glass-ceramic seals to mica-based seals that can withstand high temperatures and pressures. The mica seal maintains its structural integrity and sealing properties under the extreme operating conditions (high temperature and pressure) where conventional seals fail, thereby achieving reliable leak-tightness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite sealing structure combining mica with metal components (such as nickel or stainless steel) to create a seal system that leverages the high-temperature stability of mica and the mechanical strength of metal. This composite approach ensures both electrical insulation and reliable sealing under high pressure and temperature conditions.

Inventive Principle:
Principle #40Composite materials

2Reliability

If complex pressurized chambers are used to maintain operation under pressure, then leak-tightness is maintained, but device complexity and cost increase

Engineering Contradiction:
Improveleak-tightness under pressureVSAvoidpressurized chamber structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts and eliminates the complex pressurized chamber structure by using mica-based seals that inherently maintain leak-tightness under pressure without requiring additional containment structures. The mica seal directly handles the high-pressure sealing requirement, allowing the system to operate under pressure with minimal structural complexity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The mica-based seal system is self-sufficient in maintaining leak-tightness under pressure and temperature conditions without requiring external pressurized chambers or additional sealing mechanisms. The material properties of mica itself provide the necessary sealing function, making the system self-service and reducing overall device complexity.

Inventive Principle:
Principle #25Self-service

3Strength

If conventional seals are used, then basic assembly is achieved, but mechanical integrity and electrical insulation fail under high pressure and temperature

Engineering Contradiction:
Improvemechanical integrityVSAvoidhigh pressure and temperature effects
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent changes the seal material parameter to mica, which has superior resistance to high pressure and temperature compared to conventional glass or glass-ceramic seals. This material parameter change enables the seal to maintain mechanical integrity and electrical insulation properties under the harmful effects of high pressure and temperature operating conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite construction combining mica with metal components to create a seal system that resists high pressure and temperature. The mica provides thermal stability and electrical insulation, while the metal components provide mechanical strength, together maintaining mechanical integrity under extreme operating conditions.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The module simplifies production and implementation by eliminating the need for a pressurized chamber, maintaining leak-tightness and efficient gas distribution across varying pressures, while ensuring mechanical integrity and electrical insulation, thus enabling stable operation at high temperatures.

Implementation Method 1

a compression piston (20) mounted so as to slide inside the first interconnector (5.1), the piston being suitable for compressing the electrical contact element(s)

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 2

a sealing bellows, assembled by one end thereof to the piston and by the other end thereof to the first interconnector (5.1); the bellows being suitable both for containing the pressure of the steam and the hydrogen produced inside the module and for deforming along the direction of displacement of the piston

Methodology Applied
Scientific EffectPressure differential: Pressure Gradient

Implementation Method 3

a first electrically insulating seal (61) arranged at the periphery of the individual cell and bearing both against the first interconnector and against the second interconnector

Methodology Applied
Scientific EffectElectrical insulation: Dielectric

Implementation Method 4

mechanical means for assembling the interconnectors with one another, suitable for clamping the first seal (61) by compression

Methodology Applied
Scientific EffectMechanical force decoupling: Force

Data Source

PatentUS11063268B2Reversible individual unit for electrolysis or co-electrolysis of water (SOEC) or for fuel cell (SOFC) with operation under pressure and decoupled compressive force
Publication Date: 2021.07.13 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • US11063268B2 patent drawing
  • US11063268B2 patent drawing
  • US11063268B2 patent drawing

AI summary

The application relates to a novel module for electrolysis or co-electrolysis of water or of SOFC fuel cell, within which the forces necessary to compress the seals are decoupled from those necessary for the electrical contact elements that ensure the passage of current in the module.