SOFC-Electrolyzer Hydrogen Production for Intermittent Renewables

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Solution Overview

Problem

The intermittent supply of renewable electricity poses challenges for continuous green hydrogen production, leading to low availability factors and the need for costly storage or oversized renewable generation capacity in existing systems.

Innovation Solution

A combined hydrogen and electricity production (CHEP) system integrating high/intermediate temperature fuel cells with a water electrolyzer, allowing for continuous operation using both renewable and nonrenewable energy sources, and enabling carbon dioxide capture, with solid oxide fuel cells operating in both power generation and electrolysis modes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If renewable energy facilities operate independently for green hydrogen production, then green hydrogen can be produced with low carbon emissions, but the intermittent supply causes low availability factors and requires costly storage or oversized capacity

Engineering Contradiction:
Improvecarbon emissionsVSAvoidavailability factor
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent combines renewable energy facilities with natural gas-based steam methane reforming (SMR) plants to create an integrated hydrogen production system. This merging allows the system to produce hydrogen continuously by using natural gas as a backup when renewable energy is unavailable, thereby eliminating the intermittency problem while maintaining low carbon emissions through optimized operation modes and carbon capture technology.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The integrated system serves multiple functions: it produces hydrogen through both renewable electrolysis and natural gas reforming, generates electricity from both sources, captures carbon dioxide, and can operate in different modes (renewable-only, natural gas-only, or hybrid) depending on availability and demand. This multi-functionality resolves the contradiction by making the system adaptable to varying renewable energy supply conditions.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If renewable energy capacity is oversized to ensure continuous hydrogen production, then availability is improved, but capital costs and system complexity increase significantly

Engineering Contradiction:
Improveavailability factorVSAvoidsystem capacity configuration
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The system dynamically adjusts the contribution of renewable energy and natural gas based on real-time availability and demand conditions. During periods of high renewable availability, the system operates primarily on renewable energy; during low availability periods, it automatically transitions to natural gas supplementation. This dynamic operation eliminates the need for permanently oversized renewable capacity while maintaining continuous hydrogen production.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The system changes operational parameters (production mode, energy source mix, carbon capture intensity) based on external conditions such as renewable energy availability, hydrogen demand, and economic factors. This flexibility allows the system to maintain high availability without requiring fixed oversized capacity, thereby reducing capital costs and simplifying system configuration.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If electrolyzers operate only during renewable energy availability, then green hydrogen production is achieved, but electrolyzer utilization and lifetime are reduced due to frequent shutdowns

Engineering Contradiction:
Improvecarbon emissionsVSAvoidelectrolyzer lifetime
Core Design Contradiction:
Object-affected harmful factorsVSDuration of action of stationary object

Solution Approach 1:

The integrated system enables continuous operation of electrolyzers by providing a hybrid energy supply that combines renewable energy with natural gas-based power generation. When renewable energy is unavailable, the natural gas component ensures continuous power supply to the electrolyzer, eliminating frequent shutdowns and extending equipment lifetime while maintaining green hydrogen production during renewable availability periods.

Inventive Principle:
Principle #20Continuity of useful action

4Productivity

If natural gas is used for hydrogen production, then continuous supply and base load operation are achieved, but carbon dioxide emissions increase significantly

Engineering Contradiction:
Improvehydrogen production continuityVSAvoidcarbon dioxide emissions
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The system captures carbon dioxide emissions from natural gas-based steam methane reforming and converts this harmful byproduct into a valuable resource. The captured CO2 is utilized in enhanced oil recovery operations or other industrial applications, thereby transforming the environmental disadvantage of natural gas hydrogen production into an economic benefit while reducing net carbon emissions.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach eliminates the need for daily shutdowns, increases electrolyzer lifetime, tailors hydrogen production to end-user demand, and enhances efficiency by utilizing both renewable and nonrenewable power sources while capturing CO2, thereby providing a stable and efficient hydrogen supply.

Implementation Method 1

generating electricity and a reformed hydrogen stream in a solid oxide fuel cell (SOFC) stack

Methodology Applied
Scientific EffectFuel cell electrochemical conversion: Fuel Cell

Implementation Method 2

providing the electricity to an electrolyzer to generate an electrolysis hydrogen stream

Methodology Applied
Scientific EffectWater electrolysis: Electrolysis

Data Source

PatentUS20240072339A1Renewable energy integration with natural-gas based combined hydrogen and electricity production (CHEP) system and method
Publication Date: 2024.02.29 SAUDI ARABIAN OIL CO
  • US20240072339A1 patent drawing
  • US20240072339A1 patent drawing
  • US20240072339A1 patent drawing

AI summary

A method and a system for integrating renewable power with a natural gas hydrogen production plant are provided. An exemplary method include generating electricity and a reformed hydrogen stream in a solid oxide fuel cell (SOFC) stack, and providing the electricity to an electrolyzer to generate an electrolysis hydrogen stream. A second stream of electricity is generated in a renewable energy facility, when available, and providing the second stream of electricity to the electrolyzer to increase the generation of the electrolysis hydrogen stream.