Silicon-On-Insulator Annealing for Bonding Interface

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Solution Overview

Problem

Current methods for fabricating silicon-on-insulator (SOI) substrates with thin buried oxide layers fail to achieve complete stabilization of the oxide/oxide bonding interface, leading to defects and suboptimal electrical performance, while high-temperature treatments cause damage and stress.

Innovation Solution

A process involving two successive rapid thermal annealing (RTA) steps with specific temperature ranges and durations is applied to the silicon-on-insulator structure, where the first RTA is less aggressive than the second, ensuring complete closure of the bonding interface without surface degradation, and optionally including a stabilization anneal between the RTAs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single high-temperature RTA treatment is applied to stabilize the oxide/oxide bonding interface, then the bonding interface stabilization is improved, but surface roughness increases and damage such as slip lines and pin marks occurs

Engineering Contradiction:
Improvebonding interface stabilizationVSAvoidsurface roughness and damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The single high-temperature RTA treatment is divided into two sequential RTA steps with different temperature profiles. The first RTA step is performed at a lower temperature (e.g., 1000-1200°C) to minimize surface damage, while the second RTA step is performed at a higher temperature (e.g., 1200-1400°C) to achieve complete bonding interface stabilization. This segmentation allows the process to achieve both goals without the harmful effects of a single aggressive high-temperature treatment.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first RTA step performs a preliminary stabilization of the bonding interface at a moderate temperature, preparing the interface for the second, more aggressive RTA step. This preliminary action reduces the burden on the second step, allowing it to achieve complete stabilization with less excessive heating, thereby reducing surface damage and roughness.

Inventive Principle:
Principle #10Preliminary action

2Device complexity

If conventional single RTA treatment is used, then the process complexity is reduced, but the bonding interface is not completely stabilized leading to defects

Engineering Contradiction:
Improveprocess complexityVSAvoidbonding interface stabilization
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The bonding interface stabilization process is segmented into two distinct RTA steps, each with optimized temperature and time parameters. The first step provides initial stabilization, and the second step completes the stabilization process. This segmentation ensures complete interface stabilization while maintaining reasonable process complexity through systematic parameter optimization.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the thermal parameters (temperature and time) between the two RTA steps to achieve different objectives. The first RTA uses moderate parameters for preliminary stabilization, while the second RTA uses higher parameters for complete stabilization. This parameter variation ensures reliable bonding interface stabilization without requiring excessively complex process control.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If high-temperature treatment is applied to ensure complete closure of bonding interface, then the microscopic stabilization is improved, but macroscopic damage and stress increase

Engineering Contradiction:
Improvebonding interface closureVSAvoidmechanical stress and damage
Core Design Contradiction:
Stability of the object's compositionVSStress or pressure

Solution Approach 1:

The high-temperature treatment is segmented into two steps where the first step performs preliminary interface closure at moderate temperature, reducing the stress burden. The second step then completes the closure at higher temperature with reduced overall stress accumulation, preventing macroscopic damage while achieving microscopic stabilization.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first RTA step performs preliminary interface closure and stress relief at moderate temperature, preparing the structure for the second high-temperature step. This preliminary action prevents excessive stress accumulation during the second step, allowing complete interface closure without macroscopic damage.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively stabilizes the oxide/oxide bonding interface, minimizing defects and surface roughness, and enhancing the electrical performance of the substrates for microelectronic and optoelectronic applications.

Implementation Method 1

two successive rapid thermal annealing (RTA) steps with specific temperature ranges and durations is applied to the silicon-on-insulator structure

Methodology Applied
Scientific EffectRapid thermal annealing: Annealing

Implementation Method 2

The bond is conventionally strengthened by supplying thermal energy, which helps form covalent bonds between the two bonded surfaces

Methodology Applied
Scientific EffectThermal energy: Heating

Implementation Method 3

supplying thermal energy, which helps form covalent bonds between the two bonded surfaces

Methodology Applied
Scientific EffectCovalent bonding: Chemical Bonding

Data Source

PatentUS8691662B2Process for fabricating a silicon-on-insulator structure employing two rapid thermal annealing processes, and related structures
Publication Date: 2014.04.08 SOITEC SA
  • US8691662B2 patent drawing
  • US8691662B2 patent drawing
  • US8691662B2 patent drawing

AI summary

A method for fabricating a silicon-on-insulator structure includes forming a first oxide layer on a silicon donor substrate, forming a second oxide layer on a supporting substrate, and forming a weakened zone in the donor substrate. The donor substrate is bonded to the supporting substrate by establishing direct contact between the first oxide layer on the silicon donor substrate and the second oxide layer on the supporting substrate and establishing a direct oxide-to-oxide bond therebetween. The donor substrate is split along the weakened zone to form a silicon-on-insulator structure, and the silicon-on-insulator structure is subjected to two successive rapid thermal annealing processes at temperatures T1 and T2, respectively, wherein T1 is less than or equal to T2, T1 is between 1200° C. and 1300° C., T2 is between 1240° C. and 1300° C., and when T1 is below 1240° C., then T2 is above 1240° C.