Bonded SOI Wafer Gettering via Carbon-Induced Interface Defects

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Solution Overview

Problem

Conventional gettering techniques for SOI wafers are insufficient due to the insulating layer hindering heavy-metal impurity removal, leading to increased production costs and complex processes.

Innovation Solution

A method involving bonding SOI wafers in a state where organics exist on the surface, allowing carbon-induced micro crystal defects to form at the interface during heat treatment, which acts as a gettering source without adding extra processes, using pre-bonding SC-1 cleaning in an atmosphere containing N-methyl-2-pyrrolidone to trap organics and create crystal defects for effective impurity removal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional gettering techniques are applied to SOI wafers with an insulating layer, then the structure provides electrical isolation, but the insulating layer hinders heavy-metal impurity movement resulting in insufficient gettering effect

Engineering Contradiction:
Improveelectrical isolationVSAvoidheavy-metal impurity removal
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent creates a localized gettering region at the interface between the insulating layer and the substrate by introducing crystal defects specifically at this boundary. The bulk insulating layer maintains its electrical isolation property, while the interface region acquires heavy-metal trapping capability through defect engineering, thus resolving the contradiction between electrical isolation and impurity removal.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The interface region acts as an intermediary between the insulating layer and the substrate, serving as a dedicated gettering zone. Crystal defects are introduced at this intermediate location to capture heavy-metal impurities that migrate from the substrate, allowing the insulating layer to maintain its electrical isolation function while the interface mediates the impurity removal process.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If a gettering source is formed at the interface between the SOI layer and the insulating layer, then effective heavy-metal impurity removal is achieved, but the manufacturing process becomes more complicated and production costs increase

Engineering Contradiction:
Improveheavy-metal impurity removalVSAvoidmanufacturing process complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent employs self-service by utilizing the existing insulating layer structure and introducing crystal defects through standard thermal processing. The interface region automatically serves as the gettering source without requiring additional deposited layers or complex processing steps, thus achieving effective impurity removal while avoiding increased manufacturing complexity.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent changes the physical-chemical parameters of the interface region by introducing crystal defects through thermal processing. This parameter change transforms the interface into an effective gettering source without altering the fundamental structure or adding complex manufacturing steps, thereby achieving impurity removal while maintaining process simplicity.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If carbon ions are implanted into the oxide film and heat treatment is performed to form precipitation nuclei, then a gettering source is created at the interface, but additional processes are required resulting in increased production cost

Engineering Contradiction:
Improveheavy-metal impurity removalVSAvoidproduction cost
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent extracts the carbon ion implantation step and replaces it with a simpler method of introducing crystal defects through thermal processing. By removing the expensive and time-consuming ion implantation process while maintaining the gettering function through interface defect creation, the production cost is reduced while still achieving effective heavy-metal impurity removal.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses a simple, low-cost thermal processing method instead of expensive carbon ion implantation. The crystal defects are created through a disposable, one-time heat treatment process that is much cheaper and faster than ion implantation, thereby reducing production cost while achieving the same gettering effect.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach forms a simple and inexpensive gettering source at the SOI layer and insulating layer interface, effectively removing heavy-metal impurities and improving withstand voltage characteristics without increasing production costs.

Implementation Method 1

heat-treating for bonding reinforcement is performed in a state where organics are trapped at an interface between the active layer wafer and the supporting wafer with the oxide film to form carbon-induced micro crystal defects

Methodology Applied
Scientific EffectDecomposition: Decomposition (biological)

Implementation Method 2

form carbon-induced micro crystal defects at an interface between the SOI layer and the oxide film

Methodology Applied
Scientific EffectNucleation: Nucleation

Implementation Method 3

performing pre-bonding SC-1 cleaning on the surface of the active layer wafer and/or on the surface of the supporting wafer with the oxide film

Methodology Applied
Scientific EffectCleaning:

Implementation Method 4

heat-treating for bonding reinforcement is performed in a state where organics are trapped at an interface

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentEP1883104B1Method for manufacturing a bonded SOI wafer
Publication Date: 2015.09.30 SUMCO CORP
  • EP1883104B1 patent drawingFigure 1
  • EP1883104B1 patent drawingFigure 2
  • EP1883104B1 patent drawingFigure 3

AI summary

A bonded SOI wafer is manufactured by performing bonding in a state where organics exist on a surface of an active layer wafer and/or on a surface of a supporting wafer and performing heat-treating for bonding reinforcement in a state where the organics are trapped at an interface between the active layer wafer and the supporting wafer to form crystal defects at an interface between the active layer wafer and the oxide film and/or at an interface between the supporting wafer and the oxide film. This allows a simple and inexpensive gettering source to be formed at the interface between an SOI layer and an insulating layer (oxide film). Also, the bonded SOI wafer of the present invention that is manufactured by this method can effectively remove heavy-metal impurities that may have a negative impact on the characteristics of the device and/or the withstand voltage characteristics of the oxide film. Therefore, the manufacturing method and the bonded SOI wafer according to the present invention can be utilized widely as an SOI wafer with improved device characteristics or as a manufacturing method thereof.