Sol-Gel Non-Stick Coating With Hard Base for Impact Resistance

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Solution Overview

Problem

Vitreous-type non-stick coatings for culinary articles have limited adhesion to metal substrates, leading to poor impact resistance and high scrap rates during manufacturing.

Innovation Solution

A discontinuous hard base of metallic or ceramic material is applied to the interior face of culinary articles, followed by a sol-gel non-stick coating with a matrix of metal polyalkoxylates and dispersed metal oxides, enhancing adhesion and impact resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a sol-gel non-stick coating is applied directly to metal substrate, then the coating provides non-stick properties, but the adhesion to the substrate is limited

Engineering Contradiction:
Improveadhesion of coatingVSAvoidimpact resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies a multi-layer composite structure consisting of a metal substrate, a discontinuous hard base layer (metallic or ceramic), and a sol-gel non-stick coating. This composite structure combines the advantages of each material: the metal substrate provides form and basic strength, the discontinuous hard base layer provides adhesion enhancement and impact resistance, and the sol-gel coating provides non-stick properties. The intermediate hard base layer acts as a transition zone that improves bonding between the substrate and coating while resisting mechanical deformation.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the non-stick coating is subjected to mechanical deformation such as impact or drilling, then the coating provides protective function, but the adhesion remains limited causing cracks and marking

Engineering Contradiction:
Improveimpact resistanceVSAvoidcoating integrity
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The discontinuous hard base layer is applied beforehand to the metal substrate before the sol-gel coating is deposited. This intermediate layer serves as a cushioning layer that absorbs and distributes mechanical stresses from impacts or drilling operations, preventing stress concentration at the coating-substrate interface. The hard base layer's higher mechanical strength and toughness allow it to withstand deformation without causing the overlying non-stick coating to crack or delaminate.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Reliability

If chemical or mechanical treatment is applied to prepare the support surface, then the adhesion is improved, but the adhesion remains limited under violent impacts

Engineering Contradiction:
Improveadhesion to supportVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent introduces a composite multi-layer structure with a discontinuous hard base layer between the metal substrate and sol-gel coating. This structural solution provides superior adhesion and impact resistance compared to surface treatments alone, while the discontinuous nature of the hard base layer (rather than a continuous layer) helps control manufacturing complexity by allowing simpler application processes and better stress distribution.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly improves the adhesion and impact resistance of the non-stick coating, reducing scrap rates and ensuring the coating's durability during mechanical deformation.

Implementation Method 1

a non-stick coating covering said hard base, wherein said non-stick coating is a vitreous type coating in the form of a continuous film and consists of a sol-gel material

Methodology Applied
Scientific EffectSol-gel process: Sol

Implementation Method 2

said non-stick coating consists of a sol-gel material comprising a matrix of at least one metal polyalkoxylate

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 3

said non-stick coating consists of a sol-gel material comprising a matrix of at least one metal polyalkoxylate and at least 5% by weight relative to the total weight of the coating of at least one metal oxide dispersed in said matrix

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentEP2334444B1Cooking item comprising a non-stick coating with improved properties of adhesion to the substrate
Publication Date: 2019.02.20 SEB SA
  • EP2334444B1 patent drawingFigure 1~2
  • EP2334444B1 patent drawingFigure 3~8
  • EP2334444B1 patent drawingFigure 9~13

AI summary

The present invention relates to a cooking item comprising a vitreous coating with improved impact-resistance properties. The present invention also relates to a method for manufacturing such an item.