Sol-Gel Metal Oxide Semiconductor Insulator Interface

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Solution Overview

Problem

Wet manufacturing methods for electronic devices often result in a high number of defects at the interface between semiconductor and insulating portions, which is undesirable for device performance.

Innovation Solution

A sol-gel process is used to form both semiconductor and insulating portions based on metal oxides, with distinct drying temperatures to achieve semiconductor and insulating characteristics, respectively, minimizing defects at their interface.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If wet manufacturing methods are used to produce semiconductor and insulating portions, then large-scale structures can be produced at atmospheric pressure with precise composition control, but the interface between semiconductor and insulating portions contains a large number of defects

Engineering Contradiction:
Improvemanufacturing process accessibilityVSAvoidinterface quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by controlling the drying temperature of the gel layer to be below a critical temperature threshold. This temperature parameter control prevents the formation of excessive defects at the interface between semiconductor and insulating portions, while still allowing wet manufacturing methods to be used for producing large-scale structures at atmospheric pressure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transitions during the sol-gel drying process. By controlling the drying temperature to remain below a critical threshold, the phase transition of the gel occurs in a controlled manner that minimizes interface defects. The controlled evaporation and drying phases ensure proper formation of the metal oxide layers with reduced defects at the semiconductor-insulating interface.

Inventive Principle:
Principle #36Phase transitions

2Manufacturing precision

If dry manufacturing methods using PVD or CVD are used, then good quality interface can be obtained between insulating and semiconductor portions, but the process requires vacuum reactors and is more complex

Engineering Contradiction:
Improveinterface qualityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces the mechanical vacuum system required by PVD/CVD methods with a chemical sol-gel process that operates at atmospheric pressure. Instead of using vacuum reactors and complex deposition equipment, the invention uses solution-based chemistry followed by controlled drying, substituting mechanical vacuum processes with chemical processes that achieve similar interface quality.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces a gel intermediate state as a mediator between the sol solution and the final dried metal oxide structure. This gel phase allows for controlled transformation into the desired semiconductor or insulating material, enabling good interface quality without requiring complex vacuum equipment. The gel acts as an intermediary that facilitates the formation of high-quality interfaces through controlled drying rather than complex deposition processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively produces electronic devices with reduced defects at the semiconductor-insulating interface, ensuring improved device performance and precision in layer composition.

Implementation Method 1

forming at least a first portion and a second portion of a metal oxide by a sol-gel process

Methodology Applied
Scientific EffectSol-gel process: Gel

Implementation Method 2

The sol-gel process is used to form both semiconductor and insulating portions based on metal oxides

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 3

heating the first portion to a temperature higher than a first temperature so that the first portion becomes semiconductor and the heating of the second portion to a temperature lower than a second temperature

Methodology Applied
Scientific EffectThermal transformation: Heating

Implementation Method 4

heating the first portion to a temperature higher than a first temperature so that the first portion becomes semiconductor

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 5

the interface between the semiconductor portion and the insulating portion comprises few defects

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentEP3175484B1Electronic device and its farbication method
Publication Date: 2020.05.27 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP3175484B1 patent drawingFigure 1~5A
  • EP3175484B1 patent drawingFigure 5B~7
  • EP3175484B1 patent drawingFigure 8A~8C

AI summary

The invention relates to an electronic device (10) comprising at least a first portion (18) comprising a metal oxide that is in contact with a second portion (16) comprising said metal oxide, the first portion being semiconducting and the second portion being electrically insulating.