Sol-Gel Silane Coatings for Solar Glass Anti-Reflective and Self-Cleaning

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Solution Overview

Problem

Current anti-reflective coatings for optical elements like solar panels and windows suffer from issues such as dirt adhesion, abrasion, and limited durability, requiring frequent cleaning and lacking stability across the entire solar spectrum, which affects their long-term performance and efficiency.

Innovation Solution

A silane-based coating composition is developed, comprising silane precursors, solvents, and optional catalysts, which forms a sol-gel coating that is anti-reflective, self-cleaning, and abrasion-resistant, using a sol-gel process that can be applied at low temperatures, ensuring stability and adhesion to the substrate without cracking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional anti-reflective coatings are applied to optical elements, then light transmittance is improved, but dirt adhesion increases and requires frequent cleaning

Engineering Contradiction:
Improvelight transmittanceVSAvoidcleaning frequency
Core Design Contradiction:
Use of energy by moving objectVSEase of manufacture

Solution Approach 1:

The coating surface is designed to exhibit self-cleaning properties through inherent mechanisms such as hydrophobicity or photocatalytic activity, allowing it to repel or decompose dirt without requiring external cleaning intervention. This resolves the contradiction by making the system maintain its anti-reflective function automatically over time.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The surface energy, wettability, or chemical composition of the coating is modified to create a surface that simultaneously maintains optical transparency and resists dirt adhesion. By changing parameters like contact angle or surface chemistry, the coating achieves both high light transmittance and low soiling tendency.

Inventive Principle:
Principle #35Parameter changes

2Use of energy by moving object

If conventional anti-reflective coatings are used, then optical performance is improved, but abrasion resistance deteriorates

Engineering Contradiction:
Improveoptical efficiencyVSAvoidabrasion resistance
Core Design Contradiction:
Use of energy by moving objectVSStrength

Solution Approach 1:

The coating is formulated as a composite structure combining multiple materials or phases, where one component provides optical functionality and another provides mechanical durability. This layered or hybrid composition allows the coating to simultaneously achieve high light transmittance and superior abrasion resistance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Different regions or layers of the coating are assigned different properties: the surface layer may be optimized for hardness and scratch resistance, while the underlying layer provides optical transparency and anti-reflective functionality. This spatial differentiation of properties resolves the contradiction between optical performance and mechanical strength.

Inventive Principle:
Principle #3Local quality

3Use of energy by moving object

If conventional coatings are applied to maximize light transmittance, then energy generation efficiency is improved, but durability under environmental exposure deteriorates

Engineering Contradiction:
Improveenergy generation efficiencyVSAvoidweatherability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The chemical composition, cross-linking density, or molecular structure of the coating is adjusted to enhance its stability against UV radiation, moisture, and temperature variations. By modifying these parameters, the coating maintains its optical properties and protective function under prolonged environmental exposure, ensuring long-term reliability for energy generation applications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coatings provide enhanced light transmittance, reduced dirt adhesion, improved abrasion resistance, and durability, leading to increased efficiency and reduced maintenance costs for solar panels and windows by maintaining performance across the entire solar spectrum and withstanding environmental factors.

Implementation Method 1

A silane-based coating composition is developed, comprising silane precursors, solvents, and optional catalysts, which forms a sol-gel coating

Methodology Applied
Scientific EffectSol-gel process: Gel

Implementation Method 2

These coatings minimize the reflections on the surface of the glass as the light rays travel through a discontinuous dielectric gradient

Methodology Applied
Scientific EffectAnti-reflective coating effect: Anti-Reflective Coating

Implementation Method 3

The coatings also are hydrophobic and oleophobic and exhibit resistance to abrasion, UV light, heat, humidity, corrosives

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 4

The coatings also are hydrophobic and oleophobic and exhibit resistance to abrasion

Methodology Applied
Scientific EffectOleophobic effect: Hydrophobe

Implementation Method 5

exhibit resistance to abrasion, UV light, heat, humidity, corrosives

Methodology Applied
Scientific EffectUV absorption: Absorption (EM radiation)

Data Source

PatentUS8864897B2Anti-reflective and anti-soiling coatings with self-cleaning properties
Publication Date: 2014.10.21 FIRST SOLAR INC
  • US8864897B2 patent drawing
  • US8864897B2 patent drawing
  • US8864897B2 patent drawing

AI summary

The embodiments of the invention are directed to coatings and their uses. More particularly, the embodiments of the invention are directed to coating compositions that include silane-based precursors that are used to form coatings through a sol-gel process. The coating comprise a dried gel formed from a sol comprising a hydrolyzed alkoxysilane, a hydrolyzed organosilane, and a hydrolyzed organofluorosilane, wherein the hydrolyzed organosilane and the hydrolyzed organofluorosilane are each separately prepared before combining with each other and with alkoxysilane or with another reagent. The coatings so formed are characterized by anti-reflective, abrasion resistant, and anti-soiling properties. The coatings also have extended weatherability to heat, humidity, and protection against ambient corrosives. The coatings formed from the compositions described herein have wide application, including, for example, use as coatings on the outer glass of solar cells.