Solar Cell Adhesion Enhanced Layer

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Solution Overview

Problem

Conventional solar cells face challenges in enhancing adhesion between the back electrode layer and the substrate, leading to potential cracks and short circuits during the tabbing process, and in optimizing light reflection for improved power generation efficiency.

Innovation Solution

Incorporating an adhesion enhanced layer made of intrinsic amorphous or microcrystalline silicon between the back passivation layer and the back electrode layer, with a metal-silicon alloy interface, and a diffusion barrier layer to prevent aluminum diffusion, which improves adhesion and reflectance, reducing the risk of cracks and enhancing power generation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a conventional back electrode structure is used without an adhesion enhanced layer, then the device complexity is reduced, but the adhesion between the back electrode layer and substrate deteriorates, leading to potential cracks and short circuits

Engineering Contradiction:
Improveadhesion between back electrode layer and substrateVSAvoidstructure complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

An adhesion enhanced layer comprising intrinsic amorphous silicon and intrinsic microcrystalline silicon is introduced between the back electrode layer and the substrate. This intermediate layer acts as a mediator that significantly improves adhesion strength, preventing cracks and short circuits during the tabbing process while maintaining reasonable structural complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The adhesion enhanced layer utilizes a composite structure combining intrinsic amorphous silicon and intrinsic microcrystalline silicon. This composite material approach leverages the complementary properties of both silicon forms to achieve optimal adhesion enhancement between the back electrode layer and substrate.

Inventive Principle:
Principle #40Composite materials

2Power

If the back electrode layer is directly formed on the substrate, then the manufacturing process is simplified, but light reflection is insufficient, reducing power generation efficiency

Engineering Contradiction:
Improvepower generation efficiencyVSAvoidmanufacturing process complexity
Core Design Contradiction:
PowerVSEase of manufacture

Solution Approach 1:

The adhesion enhanced layer serves a dual function as an intermediary: it enhances mechanical adhesion while simultaneously improving optical performance. The layer's refractive index (3.7-4.2) creates effective light reflection at the back surface, increasing power generation efficiency without significantly complicating the manufacturing process.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention optimizes the refractive index parameter of the adhesion enhanced layer (3.7-4.2) to maximize light reflection. By controlling the optical parameters of the intermediate layer, the system achieves improved light trapping and reflection, thereby enhancing power generation efficiency.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If aluminum diffusion is not prevented, then the device structure is simpler, but the electrical performance deteriorates due to aluminum diffusion into the substrate

Engineering Contradiction:
Improveelectrical performance stabilityVSAvoidlayer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

A diffusion barrier layer is introduced as an intermediary between the back electrode layer and the substrate. This layer effectively prevents aluminum diffusion into the substrate, maintaining electrical performance stability and reliability while adding only moderate structural complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The diffusion barrier layer selectively extracts or blocks the harmful aluminum diffusion pathway while allowing the beneficial electrical connection to be maintained through the adhesion enhanced layer. This separation of functions ensures electrical performance stability without excessive structural complexity.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances the adhesion between the back electrode layer and the substrate, preventing cracks and short circuits, while optimizing light reflection to improve solar cell efficiency and reduce manufacturing costs.

Implementation Method 1

an adhesion enhanced layer positioned between the back electrode layer of the second electrode and the back passivation layer, the adhesion enhanced layer containing at least one of intrinsic amorphous silicon and intrinsic microcrystalline silicon

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

The adhesion enhanced layer may include a metal-silicon alloy layer at an interface between the adhesion enhanced layer and the back electrode layer. The metal-silicon alloy layer formed at the interface between the adhesion enhanced layer and the back electrode layer may be an aluminum-silicon alloy layer.

Methodology Applied
Scientific EffectAlloy formation: Composite Materials

Implementation Method 3

The solar cell may further include a diffusion barrier layer positioned between the back passivation layer and the adhesion enhanced layer. The diffusion barrier layer may contain silicon nitride (SiNX).

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 4

The back passivation layer may contain at least one of aluminum oxide (AlOx), silicon oxide (SiOx), silicon nitride (SiNx), and silicon oxynitride (SiOxNy).

Methodology Applied
Scientific EffectPassivation: Adsorption

Data Source

PatentUS9349884B2Solar cell
Publication Date: 2016.05.24 SHANGRAO JINKO SOLAR TECH DEV CO LTD
  • US9349884B2 patent drawing
  • US9349884B2 patent drawing
  • US9349884B2 patent drawing

AI summary

A solar cell includes a substrate, an emitter region positioned at a first surface of the substrate, a first electrode positioned on the first surface of the substrate, a back passivation layer positioned on a second surface opposite the first surface of the substrate, and a second electrode which is positioned on the back passivation layer and is electrically connected to the substrate through holes of the back passivation layer. The second electrode includes connection electrodes positioned inside the holes of the back passivation layer and a back electrode layer positioned on the connection electrodes and the back passivation layer. An adhesion enhanced layer is positioned between the back electrode layer and the back passivation layer and contains at least one of intrinsic amorphous silicon and intrinsic microcrystalline silicon.