Passivated Solar Cell Contact Structure for Lower Recombination Loss

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Solution Overview

Problem

The conversion efficiency of existing solar cells is limited by recombination losses at metal contact areas, and existing passivated contact cells, such as HIT and TOPCon cells, require further improvement.

Innovation Solution

A solar cell design incorporating a substrate with an interface passivation layer, a field passivation layer, and a conductive enhancement layer, where the conductive enhancement layer has a lower resistivity than the field passivation layer, allowing carriers to flow directly to the electrode with reduced series resistance and increased efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If a passivated contact is used to reduce recombination losses, then conversion efficiency is improved, but series resistance increases and carrier transmission is hindered

Engineering Contradiction:
Improverecombination lossVSAvoidcarrier transmission
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent divides the passivation layer into two distinct sub-layers with different functions: the first interface passivation sub-layer provides field passivation to reduce recombination losses, while the second interface passivation sub-layer incorporates a conductive enhancement layer to improve carrier transmission. This local differentiation of properties resolves the contradiction between reducing recombination and maintaining low series resistance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses a composite structure combining the field passivation layer with a conductive enhancement layer having lower resistivity (less than 0.001 Ω·cm). This composite material approach allows the system to simultaneously achieve effective field passivation and low series resistance, resolving the contradiction between energy loss reduction and carrier transmission reliability.

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If the field passivation layer is made thicker to improve passivation effect, then recombination loss is reduced, but carrier transmission path length increases and resistance increases

Engineering Contradiction:
Improverecombination lossVSAvoidcarrier transmission path
Core Design Contradiction:
Loss of energyVSLength of moving object

Solution Approach 1:

The patent creates a localized conductive path through the conductive enhancement layer positioned at the interface between the passivation layer and the electrode. This allows carriers to bypass the thicker field passivation layer through a low-resistance path, thus reducing both recombination loss and transmission path length simultaneously.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The conductive enhancement layer acts as an intermediary that facilitates carrier transport between the field passivation layer and the electrode. It provides a low-resistance bridge that shortens the effective carrier transmission path while maintaining the thickness of the field passivation layer needed for effective passivation.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Loss of energy

If more passivation layers are added to reduce recombination, then conversion efficiency is improved, but device complexity increases

Engineering Contradiction:
Improverecombination lossVSAvoidlayer structure
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The conductive enhancement layer serves multiple functions simultaneously: it reduces series resistance, provides an additional passivation interface, and creates a low-resistance carrier transport path. This multi-functionality allows the system to achieve effective passivation without proportionally increasing structural complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

Rather than uniformly increasing passivation throughout the structure, the patent locally enhances passivation quality at critical interfaces (substrate-passivation layer and passivation layer-electrode) through targeted sub-layers. This localized approach reduces recombination losses without requiring a proportional increase in overall layer complexity.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The design enhances carrier transmission rates and reduces losses, leading to improved conversion efficiency while maintaining effective field passivation and minimizing surface recombination.

Implementation Method 1

a conductive enhancement layer, at least partially disposed at a side of the first interface passivation sub-layer facing away from the substrate, and configured to enable carriers in the first interface passivation sub-layer to flow to the at least one electrode

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

the solar cell is usually passivated by a passivated contact in order to reduce the recombination therein and on the surface of the solar cell

Methodology Applied
Scientific EffectSurface passivation: Adsorption

Implementation Method 3

a field passivation layer, at least partially disposed between the interface passivation layer and the at least one electrode

Methodology Applied
Scientific EffectField effect passivation: Electric Field

Data Source

PatentUS11990555B2Solar cell
Publication Date: 2024.05.21 JINKO SOLAR CO LTD
  • US11990555B2 patent drawing
  • US11990555B2 patent drawing
  • US11990555B2 patent drawing

AI summary

The present disclosure provide a solar cell, including: a substrate, an interface passivation layer covering a rear surface of the substrate, and an electrode disposed at a side of the interface passivation layer facing away from the substrate, the interface passivation layer including a first interface passivation sub-layer corresponding to a portion of the interface passivation layer between adjacent electrodes and a second interface passivation sub-layer corresponding to a portion of the interface passivation layer where disposed between the substrate and the electrode; a field passivation layer, at least partially disposed between the interface passivation layer and the electrode; and a conductive enhancement layer, at least partially disposed at a side of the first interface passivation sub-layer away from the substrate to enable carriers in the first interface passivation sub-layer to flow to the electrode, where a resistivity of the conductive enhancement layer is smaller than a resistivity of the field passivation layer.