Solar Cell Shunt Prevention via Etching and Insulating Parts
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Solution Overview
Problem
The existing methods for fabricating solar cells often result in shunt circuits due to foreign matters like particles or second phases on the light absorbing layer, leading to efficiency degradation and unreliable connections between the light absorbing and front electrode layers.
Innovation Solution
A solar cell design that includes forming holes through the light absorbing and buffer layers via etching to remove foreign matters and an insulating part on the light absorbing layer to prevent shorts, ensuring smooth deposition of buffer layers and improving reliability.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Ease of manufacture
If foreign matters such as particles or second phases are present on the light absorbing layer, then the solar cell can be manufactured with standard deposition processes, but shunt circuits occur due to short between the light absorbing layer and the front electrode layer, degrading efficiency
Solution Approach 1:
The patent extracts and removes foreign matters (particles or second phases) from the light absorbing layer surface through etching processes before depositing the buffer layer. This prevents the foreign matters from causing shunt circuits and ensures proper electrical connection between layers.
Solution Approach 2:
The patent performs preliminary etching treatment on the light absorbing layer surface before buffer layer deposition to remove foreign matters in advance. This preliminary action prevents subsequent short circuits and ensures smooth buffer layer formation.
2Manufacturing precision
If etching is performed on the light absorbing layer to remove foreign matters, then the buffer layer can be deposited smoothly, but the light absorbing layer surface may be damaged by etchant
Solution Approach 1:
The patent applies etching selectively only to areas with foreign matters on the light absorbing layer surface, rather than uniform etching across the entire surface. This localized treatment removes contaminants while preserving the integrity of the light absorbing layer in unaffected areas.
Solution Approach 2:
The patent introduces a buffer layer as an intermediary between the light absorbing layer and the front electrode layer. The buffer layer is deposited after etching to protect the light absorbing layer surface while enabling smooth electrical connection, thus mediating between the etching process and the final electrical performance.
3Device complexity
If the buffer layer is deposited without removing foreign matters first, then the manufacturing process is simpler, but the buffer layer cannot be deposited smoothly, causing shunt circuits and efficiency degradation
Solution Approach 1:
The patent performs preliminary etching treatment on the light absorbing layer surface before buffer layer deposition to remove foreign matters in advance. This preliminary action prevents subsequent short circuits and ensures smooth buffer layer formation.
Solution Approach 2:
The patent extracts and removes foreign matters (particles or second phases) from the light absorbing layer surface through etching processes before depositing the buffer layer. This prevents the foreign matters from causing shunt circuits and ensures proper electrical connection between layers.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This approach prevents shunt circuits and enhances solar cell efficiency by ensuring the buffer layers are deposited smoothly, while also protecting the light absorbing layer from etchant damage and improving overall reliability.
Implementation Method 1
a buffer layer including cadmium sulfide (CdS) is formed on the light absorbing layer through a sputtering process
Implementation Method 2
a high resistance buffer layer including zinc oxide (ZnO) is formed on the buffer layer through the sputtering process
Implementation Method 3
a back electrode layer is formed on the substrate and patterned by a laser, thereby forming a plurality of back electrodes
Data Source
AI summary
A solar cell includes a support substrate, a back electrode layer on the support substrate, a light absorbing layer on the back electrode layer, a buffer layer on the light absorbing layer, a high resistance buffer layer on the buffer layer, and a front electrode layer on the high resistance buffer layer. An insulating part is located on a top surface of the light absorbing layer. A method of fabricating the solar cell includes forming the back electrode layer on the substrate, forming the light absorbing layer on the back electrode layer, forming the buffer layer on the light absorbing layer, oxidizing a top surface of the buffer layer, and forming the front electrode layer on the buffer layer.


