Solar Cell Window Layer with Conductive Nanoparticles

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Solution Overview

Problem

Current solar cells, particularly CIGS-based ones, face challenges in achieving improved electrical and optical properties such as low resistance and high transmittance.

Innovation Solution

Incorporating a window layer with a plurality of conductive particles, specifically a nano-particle layer, which reduces resistance and enhances transmittance through the plasmon phenomenon, allowing for a thinner layer with sufficient conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional window layer is used in solar cells, then the structure is simple and manufacturing is easy, but the resistance is high and transmittance is insufficient

Engineering Contradiction:
Improveelectrical and optical propertiesVSAvoidwindow layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The window layer is constructed as a composite material combining transparent conductive oxide (TCO) with metal nanoparticles (silver, aluminum, or copper). This composite structure integrates the transparency of TCO with the high conductivity of metal particles, simultaneously improving both optical transmittance and electrical conductivity while maintaining a relatively simple manufacturing process

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Metal particles are selectively distributed within the window layer at specific locations and concentrations. The non-uniform distribution of conductive particles creates localized conductive pathways that enhance overall conductivity without compromising the transparency of the entire window layer, thus improving electrical and optical properties without excessive complexity

Inventive Principle:
Principle #3Local quality

2Reliability

If the window layer thickness is increased to improve conductivity, then resistance decreases, but transmittance deteriorates and material usage increases

Engineering Contradiction:
ImproveconductivityVSAvoidmaterial usage
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention changes the physical and chemical parameters of the window layer by incorporating metal particles with specific size ranges (5-50 nm diameter) and controlled concentrations (0.1-5 wt%). These parameter changes enable the window layer to achieve high conductivity at reduced thickness (50-200 nm), thereby decreasing both material usage and maintaining transmittance while improving conductivity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite structure of TCO matrix with dispersed metal particles provides dual functionality: the TCO ensures transparency and basic conductivity, while the metal particles provide enhanced conductive pathways. This allows the window layer to be thinner with less material while maintaining or improving conductivity and transmittance simultaneously

Inventive Principle:
Principle #40Composite materials

3Reliability

If the window layer thickness is increased to ensure sufficient conductivity, then resistance decreases, but transmittance and processing efficiency deteriorate

Engineering Contradiction:
ImproveconductivityVSAvoidprocessing time
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

By changing the composition parameters to include metal particles with optimized size and concentration, the window layer achieves sufficient conductivity at reduced thickness. This parameter optimization allows thinner layers to be deposited more quickly while maintaining electrical performance, thereby improving processing efficiency without sacrificing conductivity

Inventive Principle:
Principle #35Parameter changes

4Quantity of substance

If a thinner window layer is used to improve transmittance and reduce material usage, then conductivity decreases, but this invention achieves sufficient conductivity at reduced thickness through conductive particles

Engineering Contradiction:
Improvematerial usageVSAvoidconductivity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The composite of TCO and metal particles creates a synergistic effect where the metal particles provide high-conductivity pathways that compensate for the reduced thickness. The metal particles act as conductive bridges that maintain electrical performance even when the overall layer thickness and material quantity are reduced

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The strategic distribution of metal particles creates localized conductive networks within the thinner window layer. These localized conductive regions provide sufficient overall conductivity without requiring increased thickness or material quantity, thus resolving the contradiction between material reduction and conductivity maintenance

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solar cell achieves improved electrical and optical properties with reduced material usage and processing time, while maintaining high performance.

Implementation Method 1

transmittance of the window layer can be improved by plasmon phenomenon caused by the conductive particles

Methodology Applied
Scientific EffectPlasmon phenomenon:

Implementation Method 2

development of solar cells converting solar energy into electric energy is in progress

Methodology Applied
Scientific EffectPhotovoltaic effect: Photovoltaic Effect

Data Source

PatentUS8829341B2Solar cell and method for manufacturing same
Publication Date: 2014.09.09 LG INNOTEK CO LTD
  • US8829341B2 patent drawing
  • US8829341B2 patent drawing
  • US8829341B2 patent drawing

AI summary

There is provided a solar cell comprising: a substrate; a rear electrode layer disposed on the substrate; a light absorption layer disposed on the rear electrode layer; and a window layer disposed on the light absorption layer, wherein the window layer includes a plurality of conductive particles. The conductive particles improve the optical and electrical properties of the window layer.