Solar mirrors having improved properties

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Solution Overview

Problem

Solar mirrors used in concentrated solar thermal power and photovoltaic systems face challenges in maximizing solar light reflection and extending their usable life due to issues with reflectance and thermal stability, leading to inefficiencies and frequent replacements.

Innovation Solution

A solar reflective coating is developed with a multilayer structure, including sublayers separated by parting layers to inhibit crystal growth and enhance optical stability, and an encapsulated coating stack with a lead-free corrosion inhibitor to protect the reflective coating from environmental degradation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single-layer reflective coating is used to simplify the structure, then the manufacturing process is easier and device complexity is reduced, but the thermal stability and optical performance deteriorate due to uncontrolled crystal growth

Engineering Contradiction:
Improvecoating structure complexityVSAvoidthermal stability
Core Design Contradiction:
Device complexityVSStability of the object's composition

Solution Approach 1:

The reflective coating is divided into multiple sublayers (e.g., Ag, Al, or other metallic layers) separated by parting layers (e.g., TiO2, SiO2, or other dielectric materials). This segmentation prevents continuous crystal growth across the entire coating thickness while maintaining high reflectivity, thereby improving thermal stability without significantly increasing manufacturing complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The coating structure uses composite materials combining metallic reflective layers with dielectric parting layers. This composite structure leverages the high reflectivity of metals and the thermal stability of dielectrics to achieve both optical performance and thermal resistance

Inventive Principle:
Principle #40Composite materials

2Device complexity

If the reflective coating is exposed directly to the environment to reduce device complexity, then manufacturing is simpler, but the durability and usable life decrease due to environmental degradation

Engineering Contradiction:
Improvecoating structure complexityVSAvoidusable life
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The reflective coating stack is nested within an encapsulant matrix that fully encapsulates the coating. This nested structure protects the sensitive metallic layers from environmental factors such as moisture, oxygen, and pollutants, significantly improving durability and usable life while adding only one manufacturing step

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

A thin film encapsulant layer is applied over the reflective coating to provide environmental protection. This thin film barrier prevents direct contact between the coating and harsh environmental conditions, enhancing reliability without substantially increasing device complexity

Inventive Principle:
Principle #30Flexible shells and thin films

3Reliability

If lead-based corrosion inhibitors are used to improve protection against environmental degradation, then reliability improves, but harmful factors increase due to lead toxicity

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidlead toxicity
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The encapsulant composition is modified by replacing lead-based corrosion inhibitors with lead-free alternatives such as calcium carbonate, magnesium hydroxide, or other environmentally friendly additives. This parameter change maintains the corrosion protection function while eliminating toxic effects

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The formulation transitions from using toxic lead compounds to employing benign materials that provide equivalent or superior protection. The harmful lead-based approach is converted into a beneficial lead-free solution that maintains reliability while eliminating environmental and health hazards

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Productivity

If high reflectance is prioritized to maximize solar light reflection, then energy efficiency improves, but thermal stability deteriorates due to increased light absorption and heat generation

Engineering Contradiction:
Improvesolar light reflection efficiencyVSAvoidthermal stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The coating is segmented into multiple thin sublayers rather than a single thick layer. This segmentation reduces the overall absorption path for incident light, maintaining high reflectance while distributing thermal stress across multiple interfaces, thereby improving thermal stability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The composite structure combines highly reflective metallic layers with thermally stable dielectric parting layers. This composition optimizes optical performance by maximizing reflection from metal layers while the dielectric layers provide thermal stability and reduce heat accumulation

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly improves the thermal stability and reflectance of solar mirrors, reducing specular-excluded reflectance and extending the usable life of the mirrors while maintaining high reflectivity, thus enhancing the efficiency and durability of solar energy concentration systems.

Implementation Method 1

sublayers separated by parting layers to inhibit crystal growth and enhance optical stability

Methodology Applied
Scientific EffectCrystal growth inhibition:

Implementation Method 2

solar mirrors reflect and concentrate solar light onto a receiving surface on the tower

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 3

an encapsulated coating stack with a lead-free corrosion inhibitor to protect the reflective coating from environmental degradation

Methodology Applied
Scientific EffectCorrosion inhibition:

Data Source

PatentEP3922614B1Solar mirrors having improved properties
Publication Date: 2024.03.20 VITRO FLAT GLASS LLC
  • EP3922614B1 patent drawingFigure 1~3
  • EP3922614B1 patent drawingFigure 2~4
  • EP3922614B1 patent drawingFigure 5~6

AI summary

An article for reflecting solar energy, comprising a coating stack comprising solar reflecting films and metal oxide films, the coating stack applied on a major surface of a glass substrate; and a protective overcoat; and a polymer encapsulant over outer wall surfaces of the coating stack, the outer surface of the protective overcoat and over peripheral edges of the coated article, the encapsulant comprising a base layer, a top layer and metallic corrosion-inhibitive material in the base layer.