Ethylene-Polymer Solar Panel Composition for UV and Chlorine Resistance

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Solution Overview

Problem

Polypropylene-based solar panels face issues with UV degradation, poor resistance to chlorinated water, and low temperature impact resistance, which affect their durability and performance in solar water heating systems, especially in desert environments with significant temperature fluctuations.

Innovation Solution

A solar panel composition comprising an ethylene-based polymer, a specific antioxidant compound, and a UV stabilizer, which enhances UV resistance, impact resistance, and weatherability, using a formulation that includes compounds from defined chemical formulas and a weight ratio of components to improve the material's properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If polypropylene is used for solar panels, then processability and price performance are improved, but UV resistance and weatherability deteriorate

Engineering Contradiction:
ImproveprocessabilityVSAvoidUV resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent uses polypropylene as the base polymer and combines it with specific antioxidants (mix of phenolic and phosphite types) and UV stabilizers to create a composite material system. This composite approach allows the polypropylene to maintain its excellent processability while the added compounds provide enhanced UV resistance and weatherability, resolving the contradiction between ease of manufacture and reliability.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If carbon black is added to screen UV, then UV protection is improved, but polymer degradation accelerates due to prodegradant effects

Engineering Contradiction:
ImproveUV protectionVSAvoidpolymer stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent acknowledges that carbon black can be prodegradant to polypropylene but converts this harmful effect into a benefit by carefully controlling the carbon black content and combining it with a specific mixture of antioxidants and UV stabilizers. The antioxidants scavenge free radicals generated by carbon black, while UV stabilizers prevent polymer chain scission, thus converting the potentially harmful prodegradant effect into effective UV protection without accelerating degradation.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent optimizes the concentration of carbon black and the specific ratios of antioxidants and UV stabilizers to achieve the right balance. By carefully adjusting these parameters, the system achieves effective UV screening while minimizing the prodegradant effects of carbon black through the protective action of the additive package.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If antioxidant additives are increased to improve chlorine resistance, then resistance to chlorinated water is improved, but low temperature ductility deteriorates

Engineering Contradiction:
Improvechlorine resistanceVSAvoidlow temperature ductility
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent uses a specific mixture of antioxidants (phenolic and phosphite types) in optimized ratios rather than simply increasing the total antioxidant content. This parameter optimization allows achieving good chlorine resistance while maintaining low temperature ductility by selecting antioxidant types and concentrations that do not excessively embrittle the polypropylene.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS10030891B2Panels formed from ethylene-based polymer compositions
Publication Date: 2018.07.24 DOW GLOBAL TECHNOLOGIES LLC
  • US10030891B2 patent drawing
  • US10030891B2 patent drawing
  • US10030891B2 patent drawing

AI summary

The invention provides a panel comprising at least the following components: a) at least one hollow container; b) an inlet; c) an outlet; and wherein the inlet is connected to the end of the at least one hollow container; and the outlet is connected to an opposite end of the at least one hollow container; and wherein the at least one hollow container comprises at least one component formed from a composition comprising the following components: A) an ethylene-based polymer; B) a compound selected from Formula 1, as described herein; and C) a compound selected from Formula 2, as described herein; and wherein the weight ratio of Component C to Component B (C/B) is greater than, or equal to, 1.