Solar Reflector Coating Structure for UV-Stable Abrasion Resistance

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Solution Overview

Problem

Solar reflectors made of flexible specular silver mirrors face issues with durability and ultraviolet degradation, leading to loss of dimensional stability and aesthetic appearance due to corrosion and UV transmission, which existing protective measures fail to adequately address.

Innovation Solution

A solar reflector construction incorporating an abrasion-resistant coating, a reflective metal layer, an adhesive layer, and a polymer film layer, where the polymer film is positioned between the abrasion-resistant coating and the reflective metal layer or the adhesive layer, providing enhanced durability and UV stability while maintaining high reflectance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If a thin layer of silver is vacuum-deposited on a flexible polymer substrate to provide high specular reflectance, then the solar reflector achieves higher reflectivity compared to aluminum, but the silver layer allows ultraviolet light transmission that degrades the polyester substrate

Engineering Contradiction:
Improvespecular reflectanceVSAvoidultraviolet degradation
Core Design Contradiction:
Illumination intensityVSObject-affected harmful factors

Solution Approach 1:

A clear polymer protective overlay is introduced as an intermediary layer between the silver reflective layer and the polyester substrate. This overlay acts as a mediator that blocks ultraviolet light from reaching and degrading the substrate while allowing the silver layer to maintain its high specular reflectance properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The solar reflector is constructed as a composite structure combining multiple materials: a flexible polyester substrate, a vacuum-deposited silver layer for reflectance, and a clear polymer protective overlay for UV protection. This composite approach allows each layer to perform its specific function while working together as an integrated system.

Inventive Principle:
Principle #40Composite materials

2Reliability

If corrosion inhibitors are incorporated into adhesives or protective film coatings to reduce silver corrosion, then the mirror's corrosion resistance is improved, but the inhibitors impart unacceptable color to the mirror over time

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidaesthetic appearance
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

A clear polymer protective overlay is positioned as an intermediary barrier between the silver layer and the corrosive environment. This overlay protects the silver from corrosion without introducing discoloring chemicals, thereby maintaining both corrosion resistance and aesthetic appearance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The harmful corrosion-inhibiting chemicals that cause discoloration are extracted from the system. Instead of using chemically active inhibitors that discolor, the patent relies on the physical barrier protection of the clear polymer overlay to prevent corrosion without compromising appearance.

Inventive Principle:
Principle #2Taking out (Extraction)

3Stability of the object's composition

If ultraviolet light absorbers are incorporated into a protective polymer overlay to reduce substrate degradation, then the polyester support stability is improved, but the absorbers aggravate silver corrosion

Engineering Contradiction:
Improvesubstrate stabilityVSAvoidcorrosion resistance
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

A clear polymer protective overlay serves as an intermediary that blocks ultraviolet light from reaching the polyester substrate without introducing UV absorbers that would contact and corrode the silver layer. The overlay provides UV protection through its inherent properties rather than chemical absorbers.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

UV absorber chemicals are extracted from the protective overlay formulation. The patent uses a clear polymer overlay that provides UV protection through its physical structure and inherent properties rather than through chemical absorbers that would be in contact with and corrode the silver layer.

Inventive Principle:
Principle #2Taking out (Extraction)

4Ease of manufacture

If conventional polymer film reflectors are used to reduce cost and improve flexibility, then manufacturing cost is reduced and design flexibility is improved, but abrasion resistance is insufficient

Engineering Contradiction:
Improvemanufacturing costVSAvoidabrasion resistance
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The reflector is constructed as a composite structure combining a flexible polymer substrate with a vacuum-deposited metal layer and a protective overlay. This composite construction maintains the cost and flexibility advantages of polymer films while adding the abrasion resistance of the protective overlay.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent uses a flexible polymer substrate with thin film layers deposited on it, maintaining the flexibility and ease of manufacture of thin film structures while adding protective functionality through the overlay layer that provides abrasion resistance.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves high solar reflectance, abrasion resistance, and mechanical integrity, reducing costs and improving design flexibility compared to conventional reflectors, while maintaining specular reflectance and preventing significant degradation from UV exposure.

Implementation Method 1

a silvered composite lamina, having a thin layer of silver vacuum-deposited on the surface of a flexible polymer substrate

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 2

a thin layer of silver, unlike a thin layer of aluminum, has a spectral window through which ultraviolet ('UV') light readily passes... The transmission of ultraviolet light through the silver layer degrades the underlying polyester substrate

Methodology Applied
Scientific EffectUltraviolet degradation: Photo-oxidation

Data Source

PatentUS10042094B2Weatherable solar reflector with high abrasion resistance
Publication Date: 2018.08.07 ALLIANCE FOR ENERGY INNOVATION LLC
  • US10042094B2 patent drawing
  • US10042094B2 patent drawing
  • US10042094B2 patent drawing

AI summary

Described herein are solar reflectors which provide a low cost reflector construction that has a unique set of attributes: high solar reflectance, abrasion resistance, UV stability, mechanical integrity, and flexibility. The abrasion resistance is enabled through incorporation of an abrasion-resistant coating into a polymer film metal mirror construction. Methods of using the solar reflectors in solar concentrating applications are also provided.