Heterogeneous Solid Acid Catalyst for Lignocellulose Hydrolysis

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Solution Overview

Problem

Current methods for converting lignocellulose into value-added chemicals, such as xylose and arabinose, face challenges including high energy input, corrosion issues, and low selectivity due to the use of dilute acid hydrolysis, enzymatic hydrolysis, and thermochemical processes, which are not cost-effective and environmentally friendly.

Innovation Solution

A one-step hydrolytic process using a heterogeneous solid acid catalyst, such as zeolites, mesoporous silica, or ion-exchange resins, to convert lignocellulose into xylose and arabinose under controlled temperature and pressure conditions, allowing for easy catalyst separation and neutral pH operation, reducing corrosion and neutralization waste.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If dilute acid hydrolysis is used to convert lignocellulose into xylose and arabinose, then the conversion process is simple, but corrosion issues and low selectivity occur

Engineering Contradiction:
Improveprocess simplicityVSAvoidcorrosion
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

A heterogeneous solid acid catalyst is introduced as an intermediary between the reactants and the reaction environment. The catalyst provides acid catalysis functionality while being physically separated from the reaction medium, eliminating direct acid contact that causes corrosion. The catalyst can be easily separated from the reaction mixture by filtration or decantation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If enzymatic hydrolysis is used to convert lignocellulose into xylose and arabinose, then selectivity is improved, but energy input and cost increase

Engineering Contradiction:
ImproveselectivityVSAvoidenergy input
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The reaction parameters (temperature, pressure, catalyst structure) are optimized to achieve high selectivity similar to enzymatic hydrolysis but with lower energy input. The heterogeneous solid acid catalyst allows operation at moderate temperatures and pressures, reducing energy consumption while maintaining product selectivity through controlled pore structure and acid site distribution.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If thermochemical processes are used to convert lignocellulose into xylose and arabinose, then conversion efficiency is improved, but environmental impact and energy consumption increase

Engineering Contradiction:
Improveconversion efficiencyVSAvoidenvironmental impact
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The process converts potential harmful byproducts and degradation products into valuable chemicals. The heterogeneous solid acid catalyst promotes selective transformation of lignocellulose components into xylose, arabinose, and other value-added chemicals while minimizing the formation of harmful degradation products. The neutral pH operation prevents formation of harmful neutralization waste.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Manufacturing precision

If heterogeneous solid acid catalyst is used to convert lignocellulose into xylose and arabinose, then selectivity and yield are improved, but catalyst separation complexity increases

Engineering Contradiction:
ImproveselectivityVSAvoidcatalyst separation
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The catalyst is designed as a heterogeneous solid material with distinct physical properties from the reaction mixture, allowing easy separation. The catalyst particles maintain structural integrity and can be separated by simple filtration or decantation. The catalyst structure is segmented into active sites and support material, providing both high selectivity and ease of separation.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process achieves high selectivity and yield of xylose and arabinose with reduced energy consumption and environmental impact, making it a cost-effective and industrially applicable method for converting lignocellulose into valuable chemicals.

Implementation Method 1

A one-step hydrolytic process using a heterogeneous solid acid catalyst, such as zeolites, mesoporous silica, or ion-exchange resins, to convert lignocellulose into xylose and arabinose

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

A one-step hydrolytic process using a heterogeneous solid acid catalyst, such as zeolites, mesoporous silica, or ion-exchange resins, to convert lignocellulose into xylose and arabinose

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS9267181B2One pot and single step hydrolytic process for the conversion of lignocellulose into value added chemicals
Publication Date: 2016.02.23 COUNCIL OF SCI & IND RES
  • US9267181B2 patent drawing
  • US9267181B2 patent drawing
  • US9267181B2 patent drawing

AI summary

The present invention provides a single step hydrolytic process for the conversion of lignocellulose, into value added chemicals wherein said process is catalyzed by at least one heterogeneous solid acid catalyst selected from a group comprising of zeolites, zeolites with Si/metal, mesoporous silica, oxides and phosphates, clays, ion-exchange resins, heteropolyacids, various sulfates, phosphates, selenates, crystalline materials and amorphous materials.