Solid Acid Water Splitting for Clean Syngas Production

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for producing synthesis gas generate significant air pollutants like carbon dioxide, particularly in artificial processes involving coal and water reactions, whereas natural processes using rock catalysts have limitations in scalability and efficiency.

Innovation Solution

A method utilizing a solid acid to adsorb water, split it into hydrogen, and react the hydrogen with a carbon compound to produce synthesis gas, mimicking natural processes while reducing environmental pollutants by using underground rock formations and specific catalysts like igneous and metamorphic rocks, metals, and electrolytes to enhance efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If artificial process using coal and water reaction is employed to produce synthesis gas, then synthesis gas can be produced, but significant air pollutants such as carbon dioxide are generated

Engineering Contradiction:
Improvesynthesis gas productionVSAvoidcarbon dioxide emissions
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the reaction system by using solid acid catalysts (such as zeolites, aluminosilicates, or metal oxides) to enable water-splitting reactions that produce synthesis gas without generating carbon dioxide. This parameter change in the catalytic system allows for clean synthesis gas production while maintaining productivity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the conventional high-temperature mechanical combustion process with a catalytic chemical reaction system. Instead of using coal combustion and water gas shift reactions, the invention employs solid acid-catalyzed water splitting to produce hydrogen and carbon monoxide, substituting the mechanical/thermal process with a cleaner chemical catalysis process.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Object-generated harmful factors

If natural process using rock catalysts is employed to produce hydrogen, then environmental pollutants are reduced, but scalability and efficiency are limited

Engineering Contradiction:
Improveenvironmental pollutant reductionVSAvoidhydrogen production efficiency
Core Design Contradiction:
Object-generated harmful factorsVSProductivity

Solution Approach 1:

The patent utilizes porous solid acid catalysts (such as zeolites with controlled pore structures) to enhance the scalability and efficiency of hydrogen production. The porous structure provides high surface area for catalytic activity while maintaining the environmental benefits of the natural process. The pore size and distribution can be controlled to optimize reaction efficiency and mass transfer.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent employs composite catalyst systems combining multiple solid acid materials (e.g., zeolites combined with metal oxides or aluminosilicates) to achieve both high catalytic activity and environmental compatibility. These composite materials leverage the complementary properties of different materials to enhance productivity while maintaining low pollutant emissions.

Inventive Principle:
Principle #40Composite materials

3Productivity

If high temperature reaction is used to split water and produce hydrogen, then hydrogen production rate increases, but energy consumption increases

Engineering Contradiction:
Improvehydrogen production rateVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent replaces high-temperature thermal energy input with solid acid catalysis to enable water splitting at lower temperatures. The catalytic mechanism provides an alternative energy pathway that reduces the activation energy barrier, allowing hydrogen production at moderate temperatures and significantly reducing energy consumption while maintaining high production rates.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the energy parameters of the reaction by introducing solid acid catalysts that enable water splitting at lower temperatures. Instead of requiring high temperature thermal energy, the catalytic system uses chemical facilitation to achieve the same transformation at reduced energy input, optimizing the energy efficiency of hydrogen production.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables continuous production of synthesis gas similar to natural gas while significantly reducing carbon dioxide emissions, addressing environmental concerns and energy needs by leveraging solid acids and rock formations.

Implementation Method 1

adsorbing water by reacting a solid acid mixture including a carbon compound and a solid acid with water or steam

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

producing hydrogen by introducing the water-adsorbed solid acid mixture into a reactor and splitting the water adsorbed on the solid acid mixture

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

producing a synthesis gas by reacting the produced hydrogen with the carbon compound in the reactor

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS10030496B2Method for producing synthetic gas by using solid acid
Publication Date: 2018.07.24 KOREA INST OF SCI & TECH
  • US10030496B2 patent drawing
  • US10030496B2 patent drawing
  • US10030496B2 patent drawing

AI summary

The present disclosure relates to a method for producing a synthesis gas using a solid acid, more particularly to a method for producing a synthesis gas using a solid acid capable of remarkably decreasing production of environmental pollutants such as carbon dioxide, which includes producing hydrogen by reacting a solid acid with water and producing a synthesis gas by reacting the produced hydrogen with a carbon compound.