Solid-State Battery Void Pressure Structure Against Delamination

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Solution Overview

Problem

Conventional batteries with solid electrolytes face challenges in achieving high capacity, excellent charge-discharge cycle characteristics, and reliability due to limitations in ion and electron conductivity, as well as the inconvenience of applying external restraining forces for capacity density and weight.

Innovation Solution

A battery design featuring a power generation element with an electrode layer, counter electrode layer, and solid electrolyte layer, where a void with internal pressure lower than 1 atm is created between the sealing material, electrode current collector, and the first surface, reducing delamination forces and enhancing mechanical strength through negative pressure and recessed electrode current collectors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an external restraining force mechanism is applied to maintain solid electrolyte conductivity, then ion and electron conductivity is improved, but capacity density per volume and weight deteriorates

Engineering Contradiction:
Improveion and electron conductivityVSAvoidcapacity density per weight
Core Design Contradiction:
ReliabilityVSWeight of moving object

Solution Approach 1:

The battery structure itself generates the restraining force through the negative pressure void, eliminating the need for external restraining mechanisms. The void's negative pressure automatically applies compressive force to the solid electrolyte, maintaining conductivity without adding external components that would increase weight.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention changes the pressure parameter by creating a negative pressure environment (lower than 1 atm) within the void. This pressure change allows the solid electrolyte to maintain high conductivity through the applied compressive force while keeping the battery structure compact and lightweight.

Inventive Principle:
Principle #35Parameter changes

2Strength

If a void with negative pressure is created between sealing material and electrode current collector, then delamination force is reduced and mechanical strength is improved, but structural complexity increases

Engineering Contradiction:
Improvemechanical strengthVSAvoidstructural complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The invention uses a negative pressure void (pneumatic principle) to apply uniform compressive force between the sealing material and electrode current collector. This pneumatic pressure distribution reduces delamination forces and improves mechanical strength without requiring complex mechanical fastening structures.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Solution Approach 2:

The electrode current collector includes a recess that curves toward the void, creating a curved interface that better distributes the negative pressure forces. This curvature improves mechanical strength by reducing stress concentration points while maintaining structural simplicity.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design achieves high battery characteristics and reliability by reducing delamination forces and improving mechanical strength, even in high-temperature and reduced-pressure environments, while maintaining battery capacity and preventing breakage.

Implementation Method 1

a void surrounded by the sealing material, the first surface, and the electrode current collector is present, an internal pressure of the void is lower than 1 atm

Methodology Applied
Scientific EffectPressure difference: Pressure Gradient

Data Source

PatentUS20230387525A1Battery, battery system and battery manufacturing method
Publication Date: 2023.11.30 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US20230387525A1 patent drawing
  • US20230387525A1 patent drawing
  • US20230387525A1 patent drawing

AI summary

The battery includes: a power generation element including a negative electrode active material layer, a positive electrode active material layer, and a solid electrolyte layer positioned between the negative electrode active material layer and the positive electrode active material layer; a sealing material that seals a first surface, which is a side surface of the power generation element; and a negative electrode current collector positioned on a side of the negative electrode active material layer in the power generation element. In the battery, a void surrounded by the sealing material, the first surface, and the negative electrode current collector is present, and the internal pressure of the void is lower than 1 atm. The negative electrode current collector includes a first recess curved to be recessed toward the void.