Solid Build Ink for Multi-Color 3D Printing

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Solution Overview

Problem

Current 3D printing technologies face challenges in printing articles with multiple colors due to differing curing rates and final hardness values of UV curable materials, which can lead to uneven shrinkage and cure rate issues.

Innovation Solution

The development of solid build inks comprising 40-70% solid acrylate, 10-45% non-curable wax, 1-15% curable wax, and a photoinitiator, with a specific ratio of non-curable to curable wax to adjust curing speed and final hardness, allowing for synchronized cure times and hardness across different colors, along with a support material of non-curable wax for scaffold deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If different colors of UV curable materials are used in 3D printing, then color diversity is improved, but curing rate uniformity deteriorates

Engineering Contradiction:
Improvecolor diversityVSAvoidcuring rate uniformity
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent modifies the chemical composition parameters of UV curable materials by incorporating both curable and non-curable waxes in specific ratios. This parameter change ensures that all color variants of the build ink exhibit identical curing characteristics, resolving the contradiction between color diversity and curing uniformity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent achieves homogeneity in curing behavior across different colored materials by formulating all build inks with the same base composition containing curable and non-curable waxes. This homogeneous formulation ensures that curing rates and final hardness values are consistent across all colors, eliminating the variability that would otherwise prevent multi-color printing

Inventive Principle:
Principle #33Homogeneity

2Adaptability or versatility

If different colors of UV curable materials are used in 3D printing, then color variety is improved, but final hardness consistency deteriorates

Engineering Contradiction:
Improvecolor varietyVSAvoidfinal hardness consistency
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The patent adjusts the compositional parameters of the UV curable materials by incorporating non-curable wax alongside curable wax. This parameter modification ensures that the final hardened state of all colored materials achieves consistent hardness values, resolving the contradiction between color variety and hardness consistency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite UV curable materials that combine curable and non-curable waxes in controlled ratios. This composite formulation allows the material to achieve uniform final hardness across different colors while maintaining color variety, as the non-curable wax component provides a consistent baseline hardness that is independent of colorant variations

Inventive Principle:
Principle #40Composite materials

3Adaptability or versatility

If UV curable materials with different colors are used, then multi-color printing capability is improved, but shrinkage uniformity deteriorates

Engineering Contradiction:
Improvemulti-color printing capabilityVSAvoidshrinkage uniformity
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The patent modifies the material composition parameters by incorporating non-curable wax into the UV curable build ink formulation. This parameter change ensures that all colored materials exhibit uniform shrinkage behavior during curing, as the non-curable wax component provides a stable dimensional reference that compensates for variations in colorant content, thereby enabling reliable multi-color printing

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enables the creation of 3D printed articles with minimal shrinkage and consistent curing rates across various colors, allowing for the production of robust and uniformly hardened objects with improved compatibility and tunability in curing profiles.

Implementation Method 1

UV curable solid inks capable of carrying diverse colorants

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

a curable wax in an amount from about 1 to about 15 percent by weight

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentUS9676952B23D printing system comprising solid build ink comprising colorant
Publication Date: 2017.06.13 GENESEE VALLEY INNOVATIONS LLC
  • US9676952B2 patent drawing
  • US9676952B2 patent drawing
  • US9676952B2 patent drawing

AI summary

A color three-dimensional (3D) printing system includes (1) a solid build ink for each of a plurality of colors, each solid build ink includes (a) a solid acrylate in an amount from about 40 to about 70 percent by weight, (b) a non-curable wax in an amount from about 10 to about 45 percent by weight, (c) a curable wax in an amount from about 1 to about 15 percent by weight, (d) a photoinitiator, and (e) a colorant; each solid build ink has a curing speed adjusted by a ratio of the non-curable wax to curable wax such that the initial curing speed and final hardness of each solid build ink is approximately the same for each of the plurality of colors, and (2) a support material includes the non-curable wax used in each build ink, the support material providing a scaffold for deposition of each build ink.