Solid Cleaning Composition Using Ionic Liquids and Polyethylene Glycol

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Solution Overview

Problem

Conventional hard surface cleaning compositions for institutional and commercial use rely on alkyl phenol ethoxylates (APEs), which are environmentally harmful due to their persistence and estrogen-like properties, necessitating a biodegradable and environmentally friendly alternative.

Innovation Solution

Development of solid cleaning compositions incorporating ionic liquids, specifically quaternized alkyl imidazolines, as a replacement for APEs, combined with polyethylene glycol as a hardening agent, which remain solid at room temperature and effectively remove soils without compromising stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If alkyl phenol ethoxylates (APEs) are used as cleaning agents, then effective soil and grease removal is achieved, but environmental harm increases due to persistence and estrogen-like properties

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidenvironmental harm
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the cleaning agent by replacing APEs with ionic liquids that have different molecular structures and properties. The ionic liquids maintain effective cleaning performance while eliminating the harmful environmental characteristics of APEs, specifically the persistence and estrogen-like properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite formulations combining ionic liquids with polyethylene glycol hardening agents and other cleaning components. This composite approach creates a new cleaning system that achieves effective soil removal without the environmental harm associated with conventional APE-based formulations.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If ionic liquids are incorporated into cleaning compositions, then environmental friendliness and biodegradability are improved, but maintaining solid form at room temperature becomes challenging

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidsolid form stability
Core Design Contradiction:
Object-affected harmful factorsVSShape

Solution Approach 1:

The patent modifies the physical state parameters by selecting specific ionic liquids and combining them with polyethylene glycol hardening agents. This combination changes the phase behavior of the composition, enabling it to maintain a solid form at room temperature despite the presence of ionic liquids, which are typically liquid at these temperatures.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite material system where ionic liquids are combined with polyethylene glycol and other solidifying agents. This composite formulation allows the composition to remain solid at room temperature while incorporating environmentally friendly ionic liquids, resolving the contradiction between environmental friendliness and physical form stability.

Inventive Principle:
Principle #40Composite materials

3Duration of action of stationary object

If conventional APEs are replaced with ionic liquids, then biodegradability is improved, but formulation complexity increases

Engineering Contradiction:
ImprovebiodegradabilityVSAvoidformulation complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent changes the chemical composition parameters by replacing APEs with specific ionic liquids and adjusting the formulation ratios of polyethylene glycol and other components. This parameter optimization achieves rapid biodegradability while managing formulation complexity through systematic composition design.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention develops a composite formulation system that integrates ionic liquids with polyethylene glycol hardening agents and auxiliary cleaning components. This composite approach achieves improved biodegradability while organizing the complexity into a structured, manageable formulation framework.

Inventive Principle:
Principle #40Composite materials

4Ease of operation

If solid block compositions are used, then handling and safety are improved, but incorporating liquid ionic liquids while maintaining solid form becomes difficult

Engineering Contradiction:
Improvehandling convenienceVSAvoidsolid form maintenance
Core Design Contradiction:
Ease of operationVSShape

Solution Approach 1:

The patent modifies the physical state parameters by combining ionic liquids with polyethylene glycol hardening agents in specific ratios. This parameter adjustment enables the composition to maintain a solid block form suitable for handling and safety, despite incorporating liquid ionic liquid components.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite material system where ionic liquids are integrated with polyethylene glycol and other solidifying components. This composite structure maintains the solid block form necessary for safe and convenient handling while incorporating the liquid ionic liquid cleaning agents.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of ionic liquids in solid cleaning compositions provides a renewable, environmentally friendly, and effective alternative to APEs, ensuring stable and efficient soil removal while maintaining a solid form at room temperature, thus addressing environmental concerns and performance.

Implementation Method 1

a hardening agent that can hydrate to bind free water in the emulsion which, optionally after heating and cooling, hardens to a solid

Methodology Applied
Scientific EffectHydration: Hydrates

Implementation Method 2

As a result of the charged species comprising the ionic fluids, they provide a highly polar medium

Methodology Applied
Scientific EffectIonic liquid polarity:

Implementation Method 3

the melt then poured into a mold and cooled to a solid form

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS8716207B2Solidification mechanism incorporating ionic liquids
Publication Date: 2014.05.06 ECOLAB USA INC

AI summary

A solid cleaning composition including an ionic liquid and a hardening agent is provided. The compositions are substantially free of alkyl phenol ethoxylates, including nonyl phenol ethoxylates. The solid cleaning compositions remain solid at room temperature despite the inclusion of ionic liquids, providing an effective, biorenewable, environmentally friendly alternative to nonyl phenol ethoxylate cleaning compositions.