Solid Cleansing Composition Using Ammonium-Carboxylic Acid Synergy

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Solution Overview

Problem

Existing antimicrobial cleansing compositions using carboxylic acids with pKa greater than 4.5 are costly and associated with odor issues, necessitating the use of fragrance systems that increase costs.

Innovation Solution

Combining ammonium salts like ammonium chloride with carboxylic acids having a pKa range of 2.5 to 4.5, such as benzoic acid, to achieve a synergistic antimicrobial effect without odor, formulated in a solid cleansing composition with a pH of 2.5 to 6.5.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional liquid or gel cleansers are used, then they can be applied to skin, but they require rinsing and leave residue that clogs pores and causes acne

Engineering Contradiction:
Improveapplication convenienceVSAvoidpore clogging and acne
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent transforms the physical state of the cleanser from liquid/gel to solid form (beads or flakes), fundamentally changing how the product is applied and removed. This parameter change eliminates the need for rinsing while preventing pore clogging, as the solid form can be easily picked off skin without leaving residue.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention utilizes phase transition by incorporating substances that melt at body temperature or slightly above, allowing the cleanser to transition from solid beads/flakes during application to liquid on skin contact, then back to solid upon drying. This phase transition enables easy application and removal without rinsing.

Inventive Principle:
Principle #36Phase transitions

2Reliability

If conventional cleansers are applied to skin, then cleaning occurs, but the skin becomes dry and tight requiring moisturizer

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidskin dryness and tightness
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent creates a composite cleanser containing multiple functional components: cleansing agents (amino acid derivatives, betaines), moisturizing agents (ceramides, fatty acids, cholesterol), and skin-conditioning agents. This composite formulation provides both effective cleaning and skin hydration in a single product, eliminating the need for separate moisturizer application.

Inventive Principle:
Principle #40Composite materials

3Reliability

If conventional cleansers are used, then they can remove dirt and oil, but they strip natural oils from skin disrupting the acid mantle

Engineering Contradiction:
Improvedirt and oil removalVSAvoidacid mantle balance
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the pH parameter of the cleanser to be slightly acidic (pH 4.0-6.0), matching the skin's natural acid mantle. This parameter change allows effective removal of dirt and oil while maintaining skin's natural protective barrier, preventing disruption of the acid mantle balance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention incorporates specific ingredients that target different aspects of skin care locally: amino acid derivatives for gentle cleansing, ceramides for barrier repair, fatty acids for moisture retention, and antioxidants for protection. Each component performs its function locally on the skin surface.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination provides rapid antimicrobial efficacy within 10 to 30 seconds, reducing microbial counts by 99.99% without the need for additional fragrance, thus lowering costs and maintaining effectiveness.

Implementation Method 1

The solid cleansing composition melts upon contact with skin, transforming from solid beads or flakes into an effective cleanser

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

The solid cleansing composition melts upon contact with skin, transforming from solid beads or flakes into an effective cleanser, then dries to form a solid residue that is easily picked off skin without rinsing

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP4493286B1A solid cleansing composition
Publication Date: 2026.05.06 UNILEVER IP HLDG BV

AI summary

The present invention relates to a solid cleansing composition. Particularly, the present invention relates to a cleansing composition that provides superior antimicrobial e.g. antibacterial, effect in consumer relevant contact time of 10 to 30 sec. The solid composition comprises select ammonium salts and one or more carboxylic acids having pKa in the range from 2.5 to 4.5; and wherein the pH of 5% solution of the composition is in the range 2.5 to 6.5.