Solid Electrolyte Membrane via Catalyst Inkjet Printing

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Solution Overview

Problem

Conventional methods for manufacturing solid electrolyte membranes in secondary batteries require complex processes such as heating or UV hardening and involve high viscosity electrolyte inks, which limit the flexibility and efficiency of battery production.

Innovation Solution

The use of an electrolyte composition containing a lithium salt and a cycloolefin-based monomer, combined with a catalyst ink that promotes ring-opening polymerization, allows for the inkjet printing of a solid electrolyte membrane without the need for hardening processes, using a low viscosity ink that can be easily manipulated.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional methods are used to manufacture solid electrolyte membranes, then the membrane structure is formed, but the process becomes complex and requires additional hardening steps

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidprocess steps
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent extracts and eliminates the separate hardening step from the conventional manufacturing process. By incorporating the hardening function into the coating composition itself through photopolymerizable monomers and oligomers, the process is simplified to a single coating operation that simultaneously forms and hardens the electrolyte membrane layer.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent merges the coating and hardening operations into a single step. The coating composition contains both the electrolyte precursors and photopolymerizable components, allowing the layer to be formed and cross-linked in one application process, thereby eliminating the need for separate hardening steps.

Inventive Principle:
Principle #5Merging (Combining)

2Strength

If high viscosity electrolyte inks are used, then the electrolyte membrane can be formed, but the flexibility and efficiency of battery production is limited

Engineering Contradiction:
Improveelectrolyte membrane formationVSAvoidproduction flexibility
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent changes the viscosity parameter of the electrolyte ink by using low-viscosity photopolymerizable monomers and oligomers as the base composition. This allows the ink to be easily applied through conventional coating methods while maintaining the ability to form a strong, functional electrolyte membrane after photopolymerization hardening.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the formation of a solid electrolyte membrane with improved strength and electrolytic characteristics, facilitating the production of thin, lightweight, and flexible batteries suitable for integrated circuit devices, while simplifying the manufacturing process and eliminating the need for additional hardening steps.

Implementation Method 1

a catalyst which is dissolved or dispersed in the organic solvent and promotes the ring-opening and polymerization reactions

Methodology Applied
Scientific EffectRing-opening polymerization: Chemical Bonding

Implementation Method 2

a lithium salt dissolved in the solvent... promotes the ring-opening and polymerization reactions

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Data Source

PatentUS9391342B2Electrolyte composition and catalyst ink and solid electrolyte membrane formed by using the same
Publication Date: 2016.07.12 SAMSUNG ELECTRONICS CO LTD
  • US9391342B2 patent drawing
  • US9391342B2 patent drawing
  • US9391342B2 patent drawing

AI summary

An electrolyte composition and catalyst ink, a solid electrolyte membrane formed by printing the electrolyte composition and catalyst ink, and a secondary battery including the solid electrolyte membrane. An electrolyte composition includes a solvent; a lithium salt dissolved in the solvent; and a cycloolefin-based monomer dissolved or dispersed in the solvent and a catalyst ink includes a catalyst that promotes the ring-opening and polymerization reactions of the cycloolefin monomers of the electrolyte composition.